Abstract:
The phase diagram of the tetramethylammonium fluoride−tetrapropylammonium fluoride−water system has been studied in the crystallization field; hydrate Me4NF·0.5Pr4NF·15H2O (m.p. 21.7 °C) with hexagonal II unit cell: a = 12.290 Å, c = 59.354 Å has been discovered and so, as predicted by Jeffrey, the hexagonal structure II framework has been confirmed experimentally.
Document Type:
Article
Language: English
Citation:
K. A. Udachin, Yu. A. Dyadin, J. Lipkowski, “The Hexagonal Structure II of Clathrate Hydrate Me4NF·0.5Pr4NF·15H2O”, Mendeleev Commun., 5:3 (1995), 97–99
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https://www.mathnet.ru/eng/mendc5048
https://www.mathnet.ru/eng/mendc/v5/i3/p97
This publication is cited in the following 3 articles:
Michael Wiebcke, Jürgen Felsche, “The tetraethylammonium cation in a double three-ring silicate heteronetwork clathrate and a polyhedral clathrate hydrate: low-temperature single-crystal X-ray diffraction studies on (NEt4)6[Si6O15]·40.8H2O and NEt4OH·9H2O”, Microporous and Mesoporous Materials, 43:3 (2001), 289
K Orzechowski, W Marczak, S Ernst, “Dielectric properties of water+2-methylpyridine solid mixtures”, Journal of Molecular Structure, 415:1-2 (1997), 45
K. A. Udachin, J. Lipkowski, “Channel polyhydrate (C2H5)4NF.11H2O”, Mendeleev Commun., 6:3 (1996), 92–93
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