Abstract:
3-O-2-Deoxy-α-D-glycosides of glycyrrhetic acid derivatives are stereoselectively synthesized via electrophilic glycosylation of triterpene alcohols by D-glucal and D-galactal acetates in the presence of anhydrous sulfonic acid cation exchange resins and lithium bromide.
Document Type:
Article
Language: English
Citation:
O. B. Flekhter, L. A. Baltina, E. V. Vasiljieva, G. A. Tolstikov, “Simplified stereoselective synthesis of triterpene 3-O-2-deoxy-α-D-glycosides”, Mendeleev Commun., 7:1 (1997), 3–5
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https://www.mathnet.ru/eng/mendc4754
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This publication is cited in the following 5 articles:
A. G. Tolstikov, G. A. Tolstikov, “Unsaturated sugars in enantiospecific synthesis of natural low-molecular bioregulators and their structural analogues”, Russ J Bioorg Chem, 33:1 (2007), 3
J. Thiem, W. Klaffke, Comprehensive Glycoscience, 2007, 313
O. B. Flekhter, L. A. Baltina, L. V. Spirikhin, I. P. Baikova, G. A. Tolstikov, “Glycosylation of betulin acetates with glycals”, Russ Chem Bull, 47:3 (1998), 513
O. B. Flekhter, L. A. Baltina, G. A. Tolstikov, “Direct stereospecific synthesis of triterpene and steroid 2-deoxy-α-glycosides”, Russ Chem Bull, 46:7 (1997), 1335
O. B. FLEKHTER, L. A. BALTINA, E. V. VASILJIEVA, G. A. TOLSTIKOV, “ChemInform Abstract: Simplified Stereoselective Synthesis of Triterpene 3‐O‐2‐Deoxy‐α‐ D‐glycosides.”, ChemInform, 28:28 (1997)