Abstract:
A palladium-561 giant cluster/HCOOH hydrogen-transfer reduction system has been found to be efficient for the liquid-phase hydrogenation of aromatic and aliphatic compounds with N=O, C≡N, C=O and C=C bonds under mild conditions; the reduction of nitriles is accompanied by metathesis of amines under unusually mild conditions.
Document Type:
Article
Language: English
Citation:
I. I. Moiseev, G. A. Tsirkov, A. E. Gekhman, M. N. Vargaftik, “Facile hydrogen-transfer reduction of multiple bonds by formic acid catalysed with a Pd-561 giant cluster”, Mendeleev Commun., 7:1 (1997), 1–3
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This publication is cited in the following 9 articles:
I. P. Stolyarov, A. E. Gekhman, I. I. Moiseev, A. Yu. Kolesnikov, E. M. Evstigneeva, V. R. Flid, “Catalytic hydroallylation of norbornadiene with allyl formate”, Russ Chem Bull, 56:2 (2007), 320
Helmut Bönnemann, K Nagabhushana, Surface and Nanomolecular Catalysis, 2006, 63
Mikhail Gorlov, Andreas Fischer, Lars Kloo, “Reaction between palladium(II) and gallium(III) halogenides in arenes: influence of halogen nature on the formation of binuclear palladium(I) clusters”, Journal of Organometallic Chemistry, 689:2 (2004), 489
K. S. Nagabhushana, H. Bönnemann, Nanostructure Science and Technology, Nanotechnology in Catalysis, 2004, 51
Helmut Bönnemann, Ryan M. Richards, “Nanoscopic Metal Particles - Synthetic Methods and Potential Applications”, Eur. J. Inorg. Chem., 2001:10 (2001), 2455
Gerard V. Smith, Ferenc Notheisz, Heterogeneous Catalysis in Organic Chemistry, 1999, 29
Ilya I. Moiseev, Tatiana A. Stromnova, Michael N. Vargaftik, Svetlana T. Orlova, Tatiana V. Chernysheva, Igor P. Stolarov, “Giant cluster catalysis: possible intermediacy of nitrene and carbene species”, Catalysis Today, 51:3-4 (1999), 595
I. I. Moiseev, T. A. Stromnova, M. N. Vargaftik, “Low-valence palladium complexes: Stoichiometric reactions and catalysis”, Russ Chem Bull, 47:5 (1998), 777
I.L Eremenko, S.E Nefedov, A.A Sidorov, M.O Ponina, P.V Danilov, T.A Stromnova, I.P Stolarov, S.B Katser, S.T Orlova, M.N Vargaftik, I.I Moiseev, Yu.A Ustynyuk, “Imido/nitrene ligands in the complexes of platinum metals”, Journal of Organometallic Chemistry, 551:1-2 (1998), 171