Abstract:
The reactions of O-TMS derivatives of 1,1-dimethylhydrazides of trifluoroacetic and benzoic acids with Me2Si(CHCl2)Cl give 2-organyl-4,4,6,6-tetramethyl-5-chloro-6λ5-sila-Δ2-dihydro-1,3,4λ4-oxadiazinium chlorides which in CDCl3 solution exhibit unexpected decomposition with the formation of Me2SiCl2, DMF and the corresponding organylcyanide.
Document Type:
Article
Language: English
Citation:
B. A. Gostevskii, O. B. Kozyreva, V. A. Pestunovich, Yu. A. Chuvashev, V. A. Lopyrev, M. G. Voronkov, “Synthesis and unusual rearrangement of 2-organyl-4,4,6,6-tetramethyl-5-chloro-6λ5-sila-Δ2-dihydro-1,3,4λ4-oxadiazinium chlorides”, Mendeleev Commun., 8:4 (1998), 157–158
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https://www.mathnet.ru/eng/mendc4706
https://www.mathnet.ru/eng/mendc/v8/i4/p157
This publication is cited in the following 3 articles:
H.C. Marsmann, F. Uhlig, Landolt-Börnstein - Group III Condensed Matter, 35F, Chemical Shifts and Coupling Constants for Silicon-29, 2008, 1191
H.C. Marsmann, F. Uhlig, Landolt-Börnstein - Group III Condensed Matter, 35F, Chemical Shifts and Coupling Constants for Silicon-29, 2008, 573
B. A. GOSTEVSKII, O. B. KOZYREVA, V. A. PESTUNOVICH, Y. A. CHUVASHEV, V. A. LOPYREV, M. G. VORONKOV, “ChemInform Abstract: Synthesis and Unusual Rearrangement of 2‐Organyl‐4,4,6,6‐tetramethyl‐5‐chloro‐6λ 5‐sila‐Δ2‐dihydro‐1,3,4λ 4‐oxadiazinium Chlorides.”, ChemInform, 29:52 (1998)
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