Abstract:
Temperature-dependent measurements according to the modified Eyring equation allowed the evaluation of the displacement selectivity of the nitro group and fluorine in the SNAr reactions of 3-nitro-5-R-benzotrifluorides (R = NO2, F) with the nucleophiles (2ArYH)·K2CO3 and ArY−K+ (Y = O, S) in DMF solutions.
Document Type:
Article
Language: English
Citation:
I. A. Khalfina, V. M. Vlasov, “Influence of the nucleophile structure on the selectivity of the nitro group and fluorine displacement in SNAr reactions”, Mendeleev Commun., 14:5 (2004), 217–219
Linking options:
https://www.mathnet.ru/eng/mendc3884
https://www.mathnet.ru/eng/mendc/v14/i5/p217
This publication is cited in the following 1 articles:
Donald W. Boerth, Anthony C. Arvanites, “Nucleophilic aromatic substitution in chlorinated aromatic systems with a glutathione thiolate model”, J. Phys. Org. Chem., 30:7 (2017), e3640
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