Abstract:
Secondary phosphine sulfides react chemo- and regiospecifically with alkyl vinyl ethers under radical conditions in the anti-Markovnikov mode giving corresponding tertiary phosphine sulfides in high yield.
Document Type:
Article
Language: English
Citation:
N. K. Gusarova, N. I. Ivanova, M. V. Bogdanova, S. F. Malysheva, N. A. Belogorlova, B. G. Sukhov, B. A. Trofimov, “Atom-economic synthesis of tertiary 2-alkoxyethylphosphine sulfides”, Mendeleev Commun., 14:5 (2004), 216–217
Linking options:
https://www.mathnet.ru/eng/mendc3883
https://www.mathnet.ru/eng/mendc/v14/i5/p216
This publication is cited in the following 9 articles:
Alexander V. Artem'ev, Ludmila A. Oparina, Nina K. Gusarova, Oksana V. Vysotskaya, Olga A. Tarasova, Yuriy V. Gatilov, Alexander I. Albanov, Boris A. Trofimov, “Dual reactivity of secondary phosphines and their chalcogenides towards 1-(vinyloxy)alkylferrocenes: the switch between α- and β-addition”, Tetrahedron, 71:13 (2015), 1998
Xiang-Qiang Pan, Jian-Ping Zou, Wen-Bin Yi, Wei Zhang, “Recent advances in sulfur- and phosphorous-centered radical reactions for the formation of S–C and P–C bonds”, Tetrahedron, 71:40 (2015), 7481
Svetlana F. Malysheva, Nina K. Gusarova, Alexander V. Artem'ev, Nataliya A. Belogorlova, Alexander I. Albanov, Tatyana N. Borodina, Vladimir I. Smirnov, Boris A. Trofimov, “Facile Non‐Catalyzed Synthesis of Tertiary Phosphine Sulfides by Regioselective Addition of Secondary Phosphine Sulfides to Alkenes”, Eur J Org Chem, 2014:12 (2014), 2516
N. K. Gusarova, S. I. Verkhoturova, T. I. Kazantseva, V. L. Mikhailenko, S. N. Arbuzova, B. A. Trofimov, “Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives”, Mendeleev Commun., 21:1 (2011), 17–18
N. K. Gusarova, S. F. Malysheva, N. A. Belogorlova, V. A. Kuimov, I. A. Ushakov, B. A. Trofimov, “Nucleophilic diaddition of secondary phosphine sulfides to acetylene and methylacetylene”, Russ Chem Bull, 58:1 (2009), 234
B. A. Trofimov, N. K. Gusarova, “Elemental phosphorus in strongly basic media as phosphorylating reagent: a dawn of halogen-free 'green' organophosphorus chemistry”, Mendeleev Commun., 19:6 (2009), 295–302
N. K. Gusarova, M. V. Bogdanova, N. I. Ivanova, N. A. Chernysheva, S. V. Yas'ko, V. G. Samoilov, S. M. Markosyan, B. A. Trofimov, “Free-radical addition of secondary phosphine sulfides to vinyl sulfides”, Russ J Gen Chem, 76:9 (2006), 1514
Nina K. Gusarova, Nina I. Ivanova, Maria V. Bogdanova, Svetlana F. Malysheva, Nataliya A. Belogorlova, Boris G. Sukhov, Boris A. Trofimov, “Atom‐Economic Synthesis of Tertiary 2‐Alkoxyethylphosphine Sulfides.”, ChemInform, 36:9 (2005)
B. G. Sukhov, N. K. Gusarova, N. I. Ivanova, M. V. Bogdanova, O. N. Kazheva, G. G. Aleksandrov, O. A. D'yachenko, L. M. Sinegovskaya, S. F. Malysheva, B. A. Trofimov, “Synthesis and structure of bis(2-phenylethyl) phosphine selenide”, J Struct Chem, 46:6 (2005), 1066
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