Abstract:
The X-ray diffraction studies and B3LYP/6-311G* calculations of the complexes of 1-boraadamantane and 4-bromo-1-boraadamantane with THF have revealed that the introduction of a halogen atom results in a shortening of the B−O bond due to intramolecular polarization.
Document Type:
Article
Language: English
Citation:
K. A. Lyssenko, V. A. Ponomarev, M. E. Gurskii, Yu. N. Bubnov, M. Yu. Antipin, “Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran”, Mendeleev Commun., 14:5 (2004), 189–191
Linking options:
https://www.mathnet.ru/eng/mendc3869
https://www.mathnet.ru/eng/mendc/v14/i5/p189
This publication is cited in the following 7 articles:
Kurt F. Hoffmann, Rayni P. Noriega, Paul D. Boyle, Marcus W. Drover, “2-Alkylphosphino-1-boraadamantanes”, Chem. Commun., 60:69 (2024), 9222
Majid El‐Hamdi, Alexey Y. Timoshkin, “Hydrogen splitting by pyramidalized 13–15 donor–acceptor cryptands: A computational study”, J Comput Chem, 40:21 (2019), 1892
Chao-Ying Gao, Dan Wang, Jian-Ping Li, Yuan Wang, Weiting Yang, “Assemblies of metal–organic frameworks based on a tetrapodal linker for luminescence sensing of tetrahydrofuran”, CrystEngComm, 18:16 (2016), 2857
Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata, “Water Entrapped inside Fullerene Cages: A Potential Probe for Evaluation of Bond Polarization”, Angew Chem Int Ed, 55:42 (2016), 13109
Yoshifumi Hashikawa, Michihisa Murata, Atsushi Wakamiya, Yasujiro Murata, “Water Entrapped inside Fullerene Cages: A Potential Probe for Evaluation of Bond Polarization”, Angewandte Chemie, 128:42 (2016), 13303
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