Abstract:
A new synthesis of 3-[(perfluoroprop-1-en-2-yl)bicyclo[2.2.1]hept-5-en-2-yl]sulfanes was developed based on the selective ring opening reaction of exo-3-thia-4,4-bis(perfluoroalkyl)tricyclo[4.2.1.02,5]non-7-ene by carbon and nitrogen nucleophiles.
Document Type:
Article
Language: English
Citation:
V. A. Petrov, “Stereoselective synthesis of 3-[(perfluoroprop-1-en-2-yl)bicyclo[2.2.1]-hept-5-en-2-yl]sulfanes”, Mendeleev Commun., 16:3 (2006), 155–157
Linking options:
https://www.mathnet.ru/eng/mendc3564
https://www.mathnet.ru/eng/mendc/v16/i3/p155
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Viacheslav Petrov, “Thiophilic ring opening reactions of 3,3-bis(trifluoromethyl)-5-alkoxy-1,2-dithiolanes under action of nucleophiles”, Journal of Fluorine Chemistry, 212 (2018), 1
A. Ulfkjaer, M. Pittelkow, Knowledge Updates 2018/1, 2018
Valentine G. Nenajdenko, Vasiliy M. Muzalevskiy, Aleksey V. Shastin, “Polyfluorinated Ethanes as Versatile Fluorinated C2-Building Blocks for Organic Synthesis”, Chem. Rev., 115:2 (2015), 973
Viacheslav A. Petrov, Will Marshall, “Simple synthesis of 1,1-bis(trifluoromethyl)cyclopropanes”, Journal of Fluorine Chemistry, 133 (2012), 61
Viacheslav A. Petrov, Will Marshall, “Remarkable effect of metal fluoride catalyst on reaction of hexafluoropropene, sulfur and vinyl ethers. Convenient synthesis of 2,2-bis(trifluoromethyl)-4-R-thietanes, 3,3-bis(trifluoromethyl)-5-R-1,2-dithiolanes and 2,2-bis(trifluoromethyl)-4-R-1,3-dithiolanes”, Journal of Fluorine Chemistry, 131:11 (2010), 1144
Viacheslav A. Petrov, William J. Marshall, “Reactions of polyfluorinated thietanes”, Journal of Fluorine Chemistry, 130:9 (2009), 780
Viacheslav Petrov, Will Marshall, “Hexafluorothioacetone based synthesis of fluorinated heterocycles”, Journal of Fluorine Chemistry, 128:7 (2007), 729
Viacheslav A. Petrov, Steve Lustig, Will Marshall, “Reactivity of fluorinated sulfur-containing heterocycles towards nucleophilic and oxidizing reagents”, Journal of Fluorine Chemistry, 128:10 (2007), 1227
Viacheslav A. Petrov, “Stereoselective Synthesis of 3‐[(Perfluoroprop‐1‐en‐2‐yl)bicyclo[2.2.1]hept‐5‐en‐2‐yl]sulfanes”, ChemInform, 37:47 (2006)