This article is cited in 5 scientific papers (total in 5 papers)
Thermal isomerisation of 1-chloro-1-fluoro-2-vinylcyclopropanes: competition between the vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl transformation
Abstract:
The gas-phase pyrolysis of 1-chloro-1-fluoro-2-vinylcyclopropane and 1-chloro-1-fluoro-2-methyl-2-vinylcyclopropane at 305–360 °C afforded 4-chloro-4-fluorocyclopentenes and chlorofluorobutadienes as a result of competitive vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl isomerisation.
Document Type:
Article
Language: English
Citation:
N. V. Volchkov, M. B. Lipkind, A. V. Zabolotskikh, A. V. Ignatenko, O. M. Nefedov, “Thermal isomerisation of 1-chloro-1-fluoro-2-vinylcyclopropanes: competition between the vinylcyclopropane–cyclopentene rearrangement and cyclopropyl–allyl transformation”, Mendeleev Commun., 16:3 (2006), 153–155
Linking options:
https://www.mathnet.ru/eng/mendc3563
https://www.mathnet.ru/eng/mendc/v16/i3/p153
This publication is cited in the following 5 articles:
Maxim S. Kobzev, Alexander A. Titov, Tatiana N. Borisova, Leonid G. Voskressensky, Alexey V. Varlamov, Massimo Christian D'Alterio, Alessio Petrone, Rafael Luque, Giovanni Talarico, “Switchable light vs. acid-induced transformations of complex framework compounds at room temperature”, Green Chem., 24:9 (2022), 3805
Yu. V. Tomilov, L. G. Menchikov, E. A. Shapiro, V. D. Gvozdev, K. N. Shavrin, N. V. Volchkov, M. B. Lipkind, M. P. Egorov, S. E. Boganov, V. N. Khabashesku, E. G. Baskir, “Carbenes, related intermediates, and small-sized cycles: contribution from Professor Nefedov's laboratory”, Mendeleev Commun., 31:6 (2021), 750–768
N. V. Volchkov, M. B. Lipkind, O. M. Nefedov, “Thermal cyclopropyl—allyl rearrangement of gem-chlorofluorocyclopropanes under gas-phase pyrolysis conditions. Formation of chlorofluoroalkenes and 2-fluorobuta-1,3-dienes”, Russ Chem Bull, 68:7 (2019), 1391
Maxim A. Novikov, Nikolai V. Volchkov, Maria B. Lipkind, Oleg M. Nefedov, “Copper(I)-catalyzed solvolysis of gem-chlorofluoro- and gem-bromofluorocyclopropanes. Preparation of 2-fluoroallylic ethers, esters and alcohols”, Journal of Fluorine Chemistry, 180 (2015), 131
N. V. Volchkov, M. A. Novikov, M. B. Lipkind, O. M. Nefedov, “CuCl-Catalyzed Isomerization of gem-Chlorofluoro-Cyclopropanes into Chlorofluoroalkenes”, Mendeleev Commun., 23:1 (2013), 19–21
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