Abstract:
Using NMR spectroscopy, we found that the reactions of 6-chloro-2-hydroxy-2-oxo-4-phenyl- and 2,6-dichloro-2-oxo-4-phenyl- benzo[e]-1,2-oxaphosphorinines with molecular bromine result in 3-bromo-6-chloro-2-hydroxy-2-oxo-4-phenyl- and 3-bromo-2,6-dichloro-2-oxo-4-phenylbenzo[e]-1,2-oxaphosphorinines in high yields.
Document Type:
Article
Language: English
Citation:
E. N. Varaksina, S. A. Mezentsev, V. F. Mironov, A. I. Konovalov, “Bromination of benzo[e]-1,2-oxaphosphorinine derivatives”, Mendeleev Commun., 16:2 (2006), 100–102
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https://www.mathnet.ru/eng/mendc3538
https://www.mathnet.ru/eng/mendc/v16/i2/p100
This publication is cited in the following 4 articles:
B.I. Roman, T.S.A. Heugebaert, C.V. Stevens, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 2014
V. F. Mironov, E. N. Varaksina, D. A. Tatarinov, A. A. Shtyrlina, A. B. Dobrynin, I. A. Litvinov, “Reaction of phosphorus pentachloride with 2,6-dichloro-4-phenylbenzo[e][1,2λ5]oxaphosphinine 2-oxide. Synthesis and steric structure of 2,2,6-trichloro-4-phenylbenzo[e][1,2λ5]oxaphosphinin-2-ylium hexachlorophosphate”, Russ J Gen Chem, 78:2 (2008), 192
D. A. Tatarinov, V. F. Mironov, E. N. Varaksina, A. I. Konovalov, “Reaction of 4-aryl-2,6-dichlorobenzo[e[1,2]oxaphosphinine 2-oxides with organomagnesium compounds as a convenient synthetic approach to (Z)-dialkyl(aryl)[2-(2-hydroxyaryl)-2-arylethenyl]phosphine oxides”, Russ J Gen Chem, 78:6 (2008), 1287
Elena N. Varaksina, Sergey A. Mezentsev, Vladimir F. Mironov, Alexander I. Konovalov, “Bromination of Benzo[e]‐1,2‐oxaphosphorinine Derivatives.”, ChemInform, 37:37 (2006)
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