Abstract:
The title reaction gives 2,6-dichloro- and 2,8-dichloro-2-oxo-4-butylbenzo[e]-1,2-oxaphosphorinines in a ratio of 9:1.
Document Type:
Article
Language: English
Citation:
E. N. Varaksina, V. F. Mironov, R. Z. Musin, A. I. Konovalov, “The reaction of hex-1-yne with 2,2,2-trichlorobenzo[d]-1,3,2-dioxaphosphole”, Mendeleev Commun., 16:2 (2006), 98–100
Linking options:
https://www.mathnet.ru/eng/mendc3537
https://www.mathnet.ru/eng/mendc/v16/i2/p98
This publication is cited in the following 10 articles:
D. A. Tatarinov, E. A. Mikulenkova, N. V. Terekhova, A. V. Nemtarev, A. P. Lyubina, A. D. Voloshina, A. S. Sapunova, A. B. Dobrynin, I. A. Litvinov, V. F. Mironov, “Synthesis and antimicrobial activity of alkyl[2-(5-chloro-2-hydroxyphenyl)hex-1-en-1-yl]diphenylphosphonium salts”, Russ Chem Bull, 73:12 (2024), 3699
A. V. Nemtarev, I. O. Nasibullin, R. R. Fayzullin, L. R. Grigor'eva, V. F. Mironov, “2,2,2-Trichloro-4-methoxy-1,3,2-benzodioxaphosphole in the reactions with terminal acetylenes”, Mendeleev Commun., 30:1 (2020), 34–37
Cheol‐Eui Kim, Taekyu Ryu, Sanghyuck Kim, Kooyeon Lee, Chang‐Hee Lee, Phil Ho Lee, “Gold‐Catalyzed Hydroarylation of Aryl Alkynylphosphonates for the Synthesis of Phosphacoumarins”, Adv Synth Catal, 355:14-15 (2013), 2873
A. S. Aniskin, A. V. Nemtarev, V. F. Mironov, “Reaction of 2′,2′,2′,2″,2″,2″-Hexabromo-1,4-di(benzo-1,3,2-dioxaphosphol-5-yl)benzene with phenylacetyleneom”, Russ J Org Chem, 49:5 (2013), 768
V. F. Mironov, A. V. Nemtarev, “Reaction of P,P,P-trihalogenbenzo-1,3,2-dioxaphospholes with terminal acetylenes: Phosphorus-carbon bond formation and the ipso-substitution of oxygen by carbon”, Ref. J. Chem., 1:1 (2011), 27
I. S. Ryzhkina, L. I. Murtazina, A. V. Nemtarev, V. F. Mironov, A. I. Konovalov, “Supramolecular water systems based on the new amphiphilic phosphacoumarins: synthesis, self-organizations and reactivity”, Mendeleev Commun., 20:3 (2010), 148–150
A. V. Nemtarev, E. N. Varaksina, V. F. Mironov, R. Z. Musin, A. I. Konovalov, “Predominant formation of 4-butyl-2,5-dichloro-2-oxo-1,2λ5-benzoxaphosphinine-6-carbonyl chloride in the reaction of 2,2,2-trichloro-1,3,2λ5-benzodioxaphosphole-5-carbonyl chloride with hex-1-yne”, Russ J Org Chem, 43:3 (2007), 468
A. V. Nemtarev, E. N. Varaksina, V. F. Mironov, R. Z. Musin, A. I. Konovalov, “Regioselectivity of the reaction of 4,6-di-tert-butyl-2,2,2-trichloro-1,3,2λ5-benzodioxaphosphole with hex-1-yne. ipso substitution of tert-butyl group”, Russ J Org Chem, 43:11 (2007), 1737
A. V. Nemtarev, V. F. Mironov, E. N. Varaksina, Yu. V. Nelyubina, M. Yu. Antipin, R. Z. Musin, A. I. Konovalov, “Pyridine and benzyltriethylammonium chloride ate-complexes of 2,2,2-trichlorobenzo[d]-1,3,2-dioxaphosphole in reactions with alk-1-ynes”, Mendeleev Commun., 17:6 (2007), 327–329
Andrey V. Nemtarev, Elena N. Varaksina, Vladimir F. Mironov, Rashid Z. Musin, Alexander I. Konovalov, “The Reaction of Hex‐1‐yne with 2,2,2‐Trichlorobenzo[d]‐1,3,2‐dioxaphosphole.”, ChemInform, 37:37 (2006)