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Mendeleev Communications, 2023, Volume 33, Issue 1, Pages 121–123
DOI: https://doi.org/10.1016/j.mencom.2023.01.038
(Mi mendc327)
 

This article is cited in 5 scientific papers (total in 5 papers)

Communications

Sodium dithionite in the regioselective reduction of the ortho-positioned nitro group in 1-R-2,4-dinitrobenzenes

M. D. Tsymliakov, A. I. Maksutova, E. N. Bezsonova, D. V. Zakharova, Yu. K. Grishin, V. A. Tafeenko, S. E. Sosonyuk, N. A. Lozinskaya

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Full-text PDF (356 kB) Citations (5)
Abstract: 1-R-2,4-Dinitrobenzenes are regioselectively reduced with sodium dithionite at near-neutral pH into the product having amino group ortho to the substituent R. Although the yields of products varied from moderate to good, the procedure does not involve the use of transition metals.
Keywords: nitro compounds, reduction, regioselectivity, dithionite, dinitroarenes, anilines.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (5.2 Mb)


Citation: M. D. Tsymliakov, A. I. Maksutova, E. N. Bezsonova, D. V. Zakharova, Yu. K. Grishin, V. A. Tafeenko, S. E. Sosonyuk, N. A. Lozinskaya, “Sodium dithionite in the regioselective reduction of the ortho-positioned nitro group in 1-R-2,4-dinitrobenzenes”, Mendeleev Commun., 33:1 (2023), 121–123
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  • https://www.mathnet.ru/eng/mendc/v33/i1/p121
  • This publication is cited in the following 5 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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