Zh. Weng, H. Wang, L. Wang, “Efficient thiocyanation of phenols and anilines in the CeBr3 / H2O2 system”, Mendeleev Commun., 33:1 (2023), 118

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Mendeleev Communications, 2023, Volume 33, Issue 1, Pages 118–120
DOI: https://doi.org/10.1016/j.mencom.2023.01.037 (Mi mendc326)

This article is cited in 4 scientific papers (total in 4 papers)

Communications

Efficient thiocyanation of phenols and anilines in the CeBr₃ / H₂O₂ system

Zh. Weng, H. Wang, L. Wang

School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China

Full-text PDF (206 kB) Citations (4)

DOI: https://doi.org/10.1016/j.mencom.2023.01.037

Graphic abstract: Efficient thiocyanation of phenols and anilines in the CeBr<sub>3</sub> / H<sub>2</sub>O<sub>2</sub> system

Abstract: An efficient electrophilic thiocyanation of phenols and anilines in the CeBr₃ / H₂O₂ system has been developed. The system CeBr₃ / H₂O₂ generates reactive brominating species which would react with NH₄SCN to deliver the active SCN cations in situ. The Br^- anion can be further oxidized to Br⁺, thereby furnishing the catalytic cycle.

Keywords: thiocyanation, phenols, anilines, CeBr₃/ H₂O₂ system, reactive brominating species, Fenton-like chemistry.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.4 Mb)

Citation: Zh. Weng, H. Wang, L. Wang, “Efficient thiocyanation of phenols and anilines in the CeBr₃ / H₂O₂ system”, Mendeleev Commun., 33:1 (2023), 118–120

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https://www.mathnet.ru/eng/mendc/v33/i1/p118

This publication is cited in the following 4 articles:

Ye Sun, Jing Wang, Yanyan Zhu, Tingting Han, Yi Liu, Hai-Yan Wang, “Nanoprobes based on optical imaging techniques for detecting biomarkers in liver injury diseases”, Coordination Chemistry Reviews, 524 (2025), 216303
Liz E. Lescano, Mario O. Salazar, Ricardo L. E. Furlan, “Chemically engineered essential oils prepared through thiocyanation under solvent-free conditions: chemical and bioactivity alteration”, Nat. Prod. Bioprospect., 14:1 (2024)
Natalia V. Moiseeva, Aleksey E. Sokolov, Ivan A. Andreev, Nina K. Ratmanova, Igor V. Trushkov, Vladimir A. Kokorekin, “Electrooxidative Thiocyanation of Hydroxy‐ and Alkoxybenzenes”, Eur J Org Chem, 2024
Guodong Ju, Guangyu Zhou, Yingsheng Zhao, “Transition-Metal-Free Regioselective Thiocyanation of Triisopropylsilane (TIPS)-Protected Phenols”, Chinese Journal of Organic Chemistry, 44:4 (2024), 1327

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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