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Mendeleev Communications, 2009, Volume 19, Issue 1, Pages 30–31
DOI: https://doi.org/10.1016/j.mencom.2009.01.012
(Mi mendc3107)
 

This article is cited in 19 scientific papers (total in 19 papers)

Trifluoromethyl derivatives of fullerene C70, C70(CF3)2, C70(CF3)8 and C70(CF3)14

T. Mutiga, E. Kemnitza, S. I. Troyanovab

a Institute of Chemistry, Humboldt University, Berlin, Germany
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Abstract: The reaction of C70 with higher C70(CF3)n or annealing of the latter followed by HPLC separation of reaction products resulted in an isolation of C70(CF3)2, C70(CF3)8 and C70(CF3)14. X-ray diffraction study revealed molecular structure of the three isomers that are compared with other known C70(CF3)n derivatives.
Document Type: Article
Language: English


Citation: T. Mutig, E. Kemnitz, S. I. Troyanov, “Trifluoromethyl derivatives of fullerene C70, C70(CF3)2, C70(CF3)8 and C70(CF3)14”, Mendeleev Commun., 19:1 (2009), 30–31
Linking options:
  • https://www.mathnet.ru/eng/mendc3107
  • https://www.mathnet.ru/eng/mendc/v19/i1/p30
  • This publication is cited in the following 19 articles:
    1. Wei Yang, Georgios Velkos, Marco Rosenkranz, Sandra Schiemenz, Fupin Liu, Alexey A. Popov, “Nd─Nd Bond in Ih and D5h Cage Isomers of Nd2@C80 Stabilized by Electrophilic CF3 Addition”, Advanced Science, 11:1 (2024)  crossref
    2. Maria P. Kosaya, Alexey V. Rybalchenko, Natalia S. Lukonina, Olga N. Mazaleva, Ilya N. Ioffe, Vitaliy Yu. Markov, Sergey I. Troyanov, Lev N. Sidorov, Nadezhda B. Tamm, Alexey A. Goryunkov, “Facile Separation, Spectroscopic Identification, and Electrochemical Properties of Higher Trifluoromethylated Derivatives of [70]Fullerene”, Chemistry — An Asian Journal, 13:15 (2018), 1920  crossref
    3. Olesya O. Semivrazhskaya, Nikita M. Belov, Alexey V. Rybalchenko, Vitaliy Yu. Markov, Ilya N. Ioffe, Natalia S. Lukonina, Sergey I. Troyanov, Erhard Kemnitz, Alexey A. Goryunkov, “Regioselective Synthesis of [6,6]‐Open and [5,6]‐Closed C70(CF3)8[CH2] Methanofullerenes with Rapid [6,6]‐to‐[5,6] Phototransformation”, Eur J Org Chem, 2018:6 (2018), 750  crossref
    4. B.W. Larson, S.H. Strauss, O.V. Boltalina, New Fluorinated Carbons: Fundamentals and Applications, 2017, 35  crossref
    5. Olesya O. Semivrazhskaya, Alexey V. Rybalchenko, Maria P. Kosaya, Natalia S. Lukonina, Olga N. Mazaleva, Ilya N. Ioffe, Sergey I. Troyanov, Nadezhda B. Tamm, Alexey A. Goryunkov, “Lower trifluoromethyl[70]fullerene derivatives: novel structural data and an survey of electronic properties”, Electrochimica Acta, 255 (2017), 472  crossref
    6. N. A. Romanova, P. A. Khavrel, L. N. Sidorov, “Thermodynamic functions for the formation of isomeric CF3 adducts of C70 and C84”, Fullerenes, Nanotubes and Carbon Nanostructures, 25:12 (2017), 678  crossref
    7. Victor A. Brotsman, Viktor P. Bogdanov, Alexey V. Rybalchenko, Evgenia P. Galanicheva, Nikita M. Belov, Vitaliy Yu. Markov, Natalia S. Lukonina, Ilya N. Ioffe, Sergey I. Troyanov, Erhard Kemnitz, Alexey A. Goryunkov, “Reductive Hydrogenation of Cs‐C70(CF3)8 and C1‐C70(CF3)10”, Chemistry — An Asian Journal, 11:13 (2016), 1945  crossref
    8. Olga V. Boltalina, Alexey A. Popov, Igor V. Kuvychko, Natalia B. Shustova, Steven H. Strauss, “Perfluoroalkylfullerenes”, Chem. Rev., 115:2 (2015), 1051  crossref
    9. Marina G. Apenova, Olesya O. Semivrazhskaya, Eugenia V. Borkovskaya, Nikita M. Belov, Ilya N. Ioffe, Vitaliy Yu. Markov, Sergey I. Troyanov, Natalia S. Lukonina, Lev N. Sidorov, Alexey A. Goryunkov, “Orienting Effect of the Cage Addends: The Case of Nucleophilic Cyclopropanation of C2‐C70(CF3)8”, Chemistry — An Asian Journal, 10:6 (2015), 1370  crossref
    10. Nikita M. Belov, Marina G. Apenova, Alexey V. Rybalchenko, Eugenia V. Borkovskaya, Natalia S. Lukonina, Alexey A. Goryunkov, Ilya N. Ioffe, Sergey I. Troyanov, Lev N. Sidorov, “Transalkylation of Higher Trifluoromethylated Fullerenes with C70: A Pathway to New Addition Patterns of C70(CF3)8”, Chemistry A European J, 20:4 (2014), 1126  crossref
    11. N. A. Romanova, M. A. Fritz, K. Chang, N. B. Tamm, A. A. Goryunkov, L. N. Sidorov, K. Scheurell, E. Kemnitz, S. I. Troyanov, “Synthesis and structures of trifluoromethyl derivatives of fullerenes C84(16) and C84(18)”, Russ Chem Bull, 63:12 (2014), 2657  crossref
    12. Kaichin Chang, Maria A. Fritz, Nadezhda B. Tamm, Alexey A. Goryunkov, Lev N. Sidorov, Chuanbao Chen, Shangfeng Yang, Erhard Kemnitz, Sergey I. Troyanov, “Synthesis, Structure, and Theoretical Study of Trifluoromethyl Derivatives of C84(22) Fullerene”, Chemistry A European J, 19:2 (2013), 578  crossref
    13. Daria V. Ignat'eva, Alexey A. Goryunkov, Ilya N. Ioffe, Lev N. Sidorov, “Trifluoromethylation of Fullerenes: Kinetic and Thermodynamic Control”, J. Phys. Chem. A, 117:48 (2013), 13009  crossref
    14. N. A. Romanova, N. B. Tamm, V. Yu. Markov, A. A. Goryunkov, L. N. Sidorov, S. I. Troyanov, “Synthesis, X-ray Structure and Mass Spectrum of Cs-C60(CF3)6”, Mendeleev Commun., 22:6 (2012), 297–298  mathnet  crossref
    15. Tatyana Mutig, Erhard Kemnitz, Sergey I. Troyanov, “Synthesis and molecular structures of heptafluoropropylated fullerenes: C70(n-C3F7)8, C70(n-C3F7)6O, and C70(C3F7)4”, Journal of Fluorine Chemistry, 131:8 (2010), 861  crossref
    16. Natalia I. Gruzinskaya, Andrey I. Silin, Anna S. Pimenova, Pavel A. Khavrel, Vitaliy Yu. Markov, Lev N. Sidorov, Erhard Kemnitz, Sergey I. Troyanov, “Synthesis and structure of cycloperfluoroalkylated derivatives of C70, C70(C2F4) and C70(C4F8)n, n = 1–6”, New J. Chem., 34:2 (2010), 243  crossref
    17. Adam D. Darwish, “Fullerenes”, Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 106 (2010), 356  crossref
    18. Nadezhda B. Tamm, Ilya N. Ioffe, Erhard Kemnitz, Sergey I. Troyanov, “Synthesis and molecular structure of pentafluoroethyl derivatives of C70: C70(C2F5)8 and C70(C2F5)10”, Dalton Trans., 2009, no. 15, 2740  crossref
    19. D. V. Ignat'eva, T. Mutig, A. A. Goryunkov, N. B. Tamm, E. Kemnitz, S. I. Troyanov, L. N. Sidorov, “New C70(CF3) n isomers (n = 12, 14, 16). Realkylation and addend rearrangements”, Russ Chem Bull, 58:6 (2009), 1146  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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