Abstract:
The trifluoromethylation of a higher fullerene mixture followed by the HPLC separation of CF3 derivatives resulted in the isolation of C76(CF3)14, C76(CF3)16 and C76(CF3)18 (two isomers), the crystal and molecular structures of which were determined by X-ray diffraction with the use of synchrotron radiation.
Citation:
N. B. Tamm, S. I. Troyanov, “Trifluoromethyl derivatives of fullerene C76, C76(CF3)14–18”, Mendeleev Commun., 20:4 (2010), 229–230
Linking options:
https://www.mathnet.ru/eng/mendc3048
https://www.mathnet.ru/eng/mendc/v20/i4/p229
This publication is cited in the following 12 articles:
Ayrat Khamatgalimov, Anna Egorova, Denis Chachkov, Valeri Kovalenko, “Radical character of non-IPR isomer 17418 (C1) of fullerene C76”, Fullerenes, Nanotubes and Carbon Nanostructures, 29:9 (2021), 678
Nadezhda B. Tamm, Victor A. Brotsman, Vitaliy Yu. Markov, Erhard Kemnitz, Sergey I. Troyanov, “Chlorination-promoted skeletal transformation of IPR C76 discovered via trifluoromethylation under the formation of non-IPR C76(CF3)nFm”, Dalton Trans., 47:20 (2018), 6898
Nadezhda B. Tamm, Daria V. Ignat'eva, Leonid A. Aslanov, Sergey I. Troyanov, “Synthesis, Isolation and Structures of Trifluoromethylated Fullerenes D2‐C76, C76(1)(CF3)10–18”, Chemistry — An Asian Journal, 13:16 (2018), 2027
Yang Wang, Sergio Díaz-Tendero, Manuel Alcamí, Fernando Martín, “Topology-Based Approach to Predict Relative Stabilities of Charged and Functionalized Fullerenes”, J. Chem. Theory Comput., 14:3 (2018), 1791
N. A. Romanova, P. A. Khavrel, L. N. Sidorov, “Thermodynamic functions for the formation of isomeric CF3 adducts of C70 and C84”, Fullerenes, Nanotubes and Carbon Nanostructures, 25:12 (2017), 678
Olga V. Boltalina, Alexey A. Popov, Igor V. Kuvychko, Natalia B. Shustova, Steven H. Strauss, “Perfluoroalkylfullerenes”, Chem. Rev., 115:2 (2015), 1051
Manolis D. Tzirakis, Michael Orfanopoulos, “Radical Reactions of Fullerenes: From Synthetic Organic Chemistry to Materials Science and Biology”, Chem. Rev., 113:7 (2013), 5262
Shangfeng Yang, Tao Wei, Nadezhda B. Tamm, Erhard Kemnitz, Sergey I. Troyanov, “Trifluoromethyl and Chloro Derivatives of a Higher Fullerene D2-C80(2): C80(CF3)12 and C80Cl28”, Inorg. Chem., 52:9 (2013), 4768
Manolis D. Tzirakis, Michael Orfanopoulos, Encyclopedia of Radicals in Chemistry, Biology and Materials, 2012
Shangfeng Yang, Chuanbao Chen, Tao Wei, Nadezhda B. Tamm, Erhard Kemnitz, Sergey I. Troyanov, “X‐ray Crystallographic Proof of the Isomer D2‐C84(5) as Trifluoromethylated and Chlorinated Derivatives, C84(CF3)16, C84Cl20, and C84Cl32”, Chemistry A European J, 18:8 (2012), 2217
M. A. Lanskikh, Yu. M. Belova, N. B. Tamm, K. Chang, E. Kemnitz, S. I. Troyanov, “Crystal and molecular structures of trifluoromethyl derivatives of fullerenes C76 and C82”, Crystallogr. Rep., 56:6 (2011), 1047
Adam D. Darwish, “Fullerenes”, Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 107 (2011), 473
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