Abstract:
A new type of stereospecific cascade cyclization was observed in the phosphorylation reaction of N,N’-bis(salicylidene)ethylenediimine with alkylenechlorophosphites, which resulted in the formation of tetracyclic hexacoordinated phosphorus derivatives containing the P–C–N fragment with a chiral carbon atom in the α-position to phosphorus.
Document Type:
Article
Language: English
Citation:
M. A. Pudovik, L. K. Kibardina, S. A. Terent'eva, A. R. Burilov, O. N. Kataeva, G. A. Chmutova, Sh. K. Latypov, O. G. Sinyashin, V. A. Alfonsov, “Stereospecific cascade cyclization reaction with the formation of tetracyclic hexacoordinated phosphorus derivatives”, Mendeleev Commun., 20:4 (2010), 226–228
Linking options:
https://www.mathnet.ru/eng/mendc3047
https://www.mathnet.ru/eng/mendc/v20/i4/p226
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Vladimir F. Mironov, Mudaris N. Dimukhametov, Sergey V. Efimov, Roza M. Aminova, Farida Kh. Karataeva, Dmitry B. Krivolapov, Ekaterina V. Mironova, Vladimir V. Klochkov, “Stereoselective PCO/POC-Rearrangement of P–C-Cage Phosphorane in the Reaction of 4,5-Dimethyl-2-(2-oxo-1,2-diphenyl)ethoxy-1,3,2-dioxaphospholane with Hexafluoroacetone”, J. Org. Chem., 81:14 (2016), 5837
Yu. I. Blokhin, K. N. Kornilov, Yu. V. Osipova, A. M. Bagautdinov, M. V. Tabardak, I. A. Lubimov, “Arene Phosphorus-Containing Macrocyclic Crown Ethers: Last Studies”, Phosphorus, Sulfur, and Silicon and the Related Elements, 188:11 (2013), 1478
Liudmila K. Kibardina, Michael A. Pudovik, Svetlana A. Terent'eva, Alexey B. Dobrynin, Alexander R. Burilov, Oleg G. Sinyashin, “Spirophosphoranes and Polycyclic Hexacoordinated Phosphorus Derivatives in the Phosphorylation Reactions of Bis(O-Hydroxyaryl)Diimines”, Phosphorus, Sulfur, and Silicon and the Related Elements, 188:1-3 (2013), 42
L. K. Kibardina, S. A. Terent'eva, A. R. Burilov, M. A. Pudovik, “Hexacoordinated phosphorus derivatives in the reaction of alkylenechlorophosphites with hydroxylated bisazomethines”, Russ J Gen Chem, 82:7 (2012), 1309
Romana Pajkert, Gerd-Volker Röschenthaler, Organophosphorus Chemistry, 2012, 322
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