Abstract:
The fullerene–metal complexes (η2-C60)MH(CO)[(+)DIOP] (M=Ir, Rh) have been prepared by the exchange reaction of PPh3 in corresponding (η2-C60)MH(CO)(PPh3)2 for the chelate optically active ligand (+)DIOP [(+)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)ethane] and their structures assigned.
Document Type:
Article
Language: English
Citation:
M. V. Tsikalova, S. V. Zheludkov, E. V. Vorontsov, V. V. Bashilov, K. K. Babievskii, V. I. Sokolov, Yu. N. Novikov, “Optically active rhodium and iridium C60 complexes containing the enantiomeric ligand (+)DIOP: (η2-C60)MH(CO)[(+)DIOP] (M=Rh, Ir)”, Mendeleev Commun., 21:5 (2011), 256–258
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https://www.mathnet.ru/eng/mendc2935
https://www.mathnet.ru/eng/mendc/v21/i5/p256
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