Abstract:
The fullerene–metal complexes (η2-C60)MH(CO)[(+)DIOP] (M=Ir, Rh) have been prepared by the exchange reaction of PPh3 in corresponding (η2-C60)MH(CO)(PPh3)2 for the chelate optically active ligand (+)DIOP [(+)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)ethane] and their structures assigned.
Document Type:
Article
Language: English
Citation:
M. V. Tsikalova, S. V. Zheludkov, E. V. Vorontsov, V. V. Bashilov, K. K. Babievskii, V. I. Sokolov, Yu. N. Novikov, “Optically active rhodium and iridium C60 complexes containing the enantiomeric ligand (+)DIOP: (η2-C60)MH(CO)[(+)DIOP] (M=Rh, Ir)”, Mendeleev Commun., 21:5 (2011), 256–258
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https://www.mathnet.ru/eng/mendc2935
https://www.mathnet.ru/eng/mendc/v21/i5/p256
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Maria A. Lebedeva, Thomas W. Chamberlain, Andrei N. Khlobystov, “Harnessing the Synergistic and Complementary Properties of Fullerene and Transition-Metal Compounds for Nanomaterial Applications”, Chem. Rev., 115:20 (2015), 11301
A. R. Tuktarov, L. M. Khalilov, K. K. Babievskii, A. R. Akhmetov, V. I. Sokolov, U. M. Dzhemilev, “Circular dichroism spectra of new optically active terpenoid spiro homofullerenes”, Mendeleev Commun., 25:4 (2015), 273–274
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