Abstract:
The [2+2] photodimerization of the complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+ under visible-light irradiation leads to a mixture of the head-to-head heptacyclene products [(μ-η6: η6-C24H16)Ru2(C5Me4CH2OMe)2]2+ (syn- and anti-) with the predominant formation of the syn-isomer; the structures of both isomers were established by X-ray diffraction analysis.
Citation:
E. E. Karslyan, A. I. Konovalov, A. O. Borissova, P. V. Petrovskii, A. R. Kudinov, “[2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+”, Mendeleev Commun., 22:4 (2012), 189–191
Linking options:
https://www.mathnet.ru/eng/mendc2785
https://www.mathnet.ru/eng/mendc/v22/i4/p189
This publication is cited in the following 3 articles:
Sjoerd J. Rijpkema, Sam Vissers, Daniela A. Wilson, “Selective photodimerization of acenaphthylene in polymersome nanoreactors”, Chem. Commun., 59:32 (2023), 4782
Dmitry S. Perekalin, Alexander R. Kudinov, “Cyclopentadienyl ruthenium complexes with naphthalene and other polycyclic aromatic ligands”, Coordination Chemistry Reviews, 276 (2014), 153
K. Yu. Koltunov, A. N. Chernov, L. A. Ostashevskaya, P. A. Gribov, “Electrophilic dimerization of naphthols in the presence of aluminum halides”, Mendeleev Commun., 24:2 (2014), 122–124
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