This article is cited in 22 scientific papers (total in 22 papers)
Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride
Abstract:
Microwave irradiation of 2-bromopyridine with red phosphorus in the superbasic KOH/DMSO (H2O) suspension affords tris(2-pyridyl)phosphine in 53% yield; two molecules of tris(2-pyridyl)phosphine coordinate with CoCl2 by their six nitrogen atoms only to form [Co(2-Py3P)2]Cl2⋅8H2O complex having two phosphorus atoms beyond the coordination sphere.
Citation:
B. A. Trofimov, N. K. Gusarova, A. V. Artem'ev, S. F. Malysheva, N. A. Belogorlova, A. O. Korocheva, O. N. Kazheva, G. G. Alexandrov, O. A. Dyachenko, “Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride”, Mendeleev Commun., 22:4 (2012), 187–188
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This publication is cited in the following 22 articles:
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S. F. Malysheva, V. A. Kuimov, S. N. Arbuzova, “Elemental Phosphorus in the Synthesis of Organophosphorus Compounds: The Recent Advances (A Review)”, Russ J Gen Chem, 93:S1 (2023), S238
T. V. Baulina, I. Yu. Kudryavtsev, M. P. Pasechnik, A. G. Matveeva, A. V. Vologzhanina, P. V. Dorovatovskii, V. K. Brel, “Tris[2-(2′-pyridylmethoxy)phenyl]phosphine Oxide: Synthesis and Coordination Properties”, Russ J Gen Chem, 93:S1 (2023), S262
Andrew J. Peel, Jessica E. Waters, Alex J. Plajer, Raúl García-Rodríguez, Dominic S. Wright, Advances in Organometallic Chemistry, 75, 2021, 193
Stanislav K. Petrovskii, Aleksandra V. Paderina, Anastasia A. Sizova, Andrey Yu. Baranov, Alexander A. Artem'ev, Vladimir V. Sizov, Elena V. Grachova, “Luminescence behaviour of Au(i)–Cu(i) heterobimetallic coordination polymers based on alkynyl-tris(2-pyridyl)phosphine Au(i) complexes”, Dalton Trans., 49:38 (2020), 13430
S. A. Adonin, A. S. Novikov, V. P. Fedin, “Crystal Structure of the Heteroligand Complex [(2-Br-5-MePy)2CoCl2] · (2-Br-5-MePy): Formation of Supramolecular Associates due to the Halogen Bond”, Russ J Coord Chem, 46:1 (2020), 37
Wisdom A Munzeiwa, Bernard Omondi, Vincent O Nyamori, “Architecture and synthesis of P,N-heterocyclic phosphine ligands”, Beilstein J. Org. Chem., 16 (2020), 362
H. Wang, N. Wu, J. Zheng, Ch. Zheng, D. Wang, “Synthesis and structures of two mononuclear iron(ii) complexes derived from polypyridine ligands”, Mendeleev Commun., 30:1 (2020), 100–102
Svetlana F. Malysheva, Vladimir A. Kuimov, Natalia A. Belogorlova, Alexander I. Albanov, Nina K. Gusarova, Boris A. Trofimov, “Superbase‐Assisted Selective Synthesis of Triarylphosphines from Aryl Halides and Red Phosphorus: Three Consecutive Different SNAr Reactions in One Pot”, Eur J Org Chem, 2019:36 (2019), 6240
I.V. Sterkhova, V.I. Smirnov, S.F. Malysheva, V.A. Kuimov, N.A. Belogorlova, “Molecular and crystal structures of tris(3-methylphenyl)phosphine and its chalcogenides”, Journal of Molecular Structure, 1197 (2019), 681
S. F. Malysheva, V. A. Kuimov, A. B. Trofimov, N. A. Belogorlova, Yu. I. Litvintsev, A. M. Belogolova, N. K. Gusarova, B. A. Trofimov, “2-Halopyridines in the triple reaction in the Pn/KOH/DMSO system to form tri(2-pyridyl)phosphine: Experimental and quantum-chemical dissimilarities”, Mendeleev Commun., 28:5 (2018), 472–474
Alexander V. Artem'ev, Alexey V. Kashevskii, Artem S. Bogomyakov, Alexander Yu. Safronov, Anastasiya O. Sutyrina, Anton A. Telezhkin, Irina V. Sterkhova, “Variable coordination of tris(2-pyridyl)phosphine and its oxide toward M(hfac)2: a metal-specifiable switching between the formation of mono- and bis-scorpionate complexes”, Dalton Trans., 46:18 (2017), 5965
S. Hanf, R. García-Rodríguez, S. Feldmann, A. D. Bond, E. Hey-Hawkins, D. S. Wright, “Multidentate 2-pyridyl-phosphine ligands – towards ligand tuning and chirality”, Dalton Trans., 46:3 (2017), 814
Teresa F. Vaughan, John L. Spencer, “Transition metal complexes of the pyridylphosphine ligand o-C6H4(CH2PPy2)2”, Dalton Trans., 45:42 (2016), 16826
S. F. Malysheva, N. A. Belogorlova, Ya. A. Vereshchagina, A. Z. Alimova, E. A. Ishmaeva, D. V. Chachkov, “Synthesis and conformational analysis of phosphine selenides”, Russ J Gen Chem, 86:3 (2016), 590
Alexander V. Artem'ev, Nina K. Gusarova, Vladimir A. Shagun, Svetlana F. Malysheva, Vladimir I. Smirnov, Tatyana N. Borodina, Boris A. Trofimov, “Complexation of tris(2-pyridyl)phosphine chalcogenides with copper(I) halides: The selective formation of scorpionate complexes, [Cu(N,N′,N″-2-Py3PX)Hal] (X=O, S and Se)”, Polyhedron, 90 (2015), 1
Timo Gneuß, Markus J. Leitl, Lars H. Finger, Nicholas Rau, Hartmut Yersin, Jörg Sundermeyer, “A new class of luminescent Cu(i) complexes with tripodal ligands – TADF emitters for the yellow to red color range”, Dalton Trans., 44:18 (2015), 8506
Svetlana N. Arbuzova, Nina K. Gusarova, Svetlana I. Verkhoturova, Tatyana I. Kazantseva, Igor A. Ushakov, Anastasiya G. Mal'kina, Boris A. Trofimov, “P-C Bond Cleavage by Hydroxyl Function during the Addition of Tris(2-pyridyl)phosphine to Cyanopropargylic Alcohols in Water”, Heteroatom Chem., 26:3 (2015), 231
Amedeo Santoro, Carlo Sambiagio, Patrick C. McGowan, Malcolm A. Halcrow, “Synthesis and coordination chemistry of 1,1,1-tris-(pyrid-2-yl)ethane”, Dalton Trans., 44:3 (2015), 1060
A. V. Artem'ev, N. K. Gusarova, S. F. Malysheva, N. A. Belogorlova, O. N. Kazheva, G. G. Alexandrov, O. A. Dyachenko, B. A. Trofimov, “Unexpected N,N'-coordination of tris(2-pyridyl)-phosphine chalcogenides to PdCl2”, Mendeleev Commun., 25:3 (2015), 196–198
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