Abstract:
Simple chiral precursors for the preparation of methylene-expanded C-nucleosides were developed, using as key steps pyrolysis of cellulose to levoglucosenone followed by hydrogenation and introduction of vinyl and ethynyl fragments to the 2-position.
Citation:
V. K. Brel, A. V. Samet, L. D. Konyushkin, A. I. Stash, V. K. Belsky, V. V. Semenov, “Levoglucosenone-derived precursors for the stereoselective synthesis of methylene-expanded analogues of C-nucleosides”, Mendeleev Commun., 25:1 (2015), 44–46
Linking options:
https://www.mathnet.ru/eng/mendc2295
https://www.mathnet.ru/eng/mendc/v25/i1/p44
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