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Communications
Magnesium dichloride effect in ethylene polymerization reactions: a comparative DFT study of Mg-containing and Mg-free post-titanocene catalytic systems
Abstract:
A DFT study of the bi- and trinuclear heterocomplexes of Ti, Al and Mg revealed a higher reactivity of Mg-containing compounds toward ethylene, as compared to Mg-free systems; this explains a significant activation effect of Mg-containing compounds on thecatalytic activity of the Ti complexes in ethylene polymerization.
Document Type:
Article
Language: English
Citation:
L. Yu. Ustynyuk, B. M. Bulychev, “Magnesium dichloride effect in ethylene polymerization reactions: a comparative DFT study of Mg-containing and Mg-free post-titanocene catalytic systems”, Mendeleev Commun., 26:1 (2016), 45–48
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https://www.mathnet.ru/eng/mendc2105
https://www.mathnet.ru/eng/mendc/v26/i1/p45
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