Abstract:
A new organic-inorganic hybrid material containing bromobismuthate anions and bis(1-pyridino)hexane cations was synthesized and characterized. The reaction between (C16H22N2)2Bi2Br10 and HBr in the presence of HI vapor afforded (C16H22N2)3(BiBr6)2 as the main product and (C16H22N2)3(BiBr6)(BiBr7I) as a by-product containing the BrIBr– anion coordinated by bismuth.
Citation:
V. Yu. Kotov, N. P. Simonenko, A. B. Ilyukhin, “Hybrid halobismuthates: a coordinated BrIBr– anion”, Mendeleev Commun., 27:5 (2017), 454–455
Linking options:
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https://www.mathnet.ru/eng/mendc/v27/i5/p454
This publication is cited in the following 17 articles:
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A. N. Usoltsev, I. V. Korol'kov, S. A. Adonin, “Bromoantimonates(III) vs. Bromobismuthates(III): Differences in the Tendency for the Formation of Polynuclear Complexes”, Russ J Coord Chem, 49:6 (2023), 345
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Igor D. Gorokh, Sergey A. Adonin, Alexander S. Novikov, Maxim N. Sokolov, Denis G. Samsonenko, Vladimir P. Fedin, “Polybromides of pyridinium and quinolinium-type cations: Cation-induced structural diversity and theoretical analysis of Br⋯Br interactions”, Journal of Molecular Structure, 1179 (2019), 725
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Vitalii Yu. Kotov, Elnara S. Safiullina, Andrey B. Ilyukhin, Petr A. Buikin, Kirill P. Birin, Khursand E. Yorov, “Hybrid halobismuthates: The unusual {[BiBr6]…[BiBr5]…[BiBr6]}8- anionic framework”, Journal of Molecular Structure, 1195 (2019), 944
V. Yu. Kotov, A. B. Ilyukhin, P. A. Buikin, Kh. E. Yorov, “Mixed halide hybrid halobismuthates and their in situ transformations”, Mendeleev Commun., 29:5 (2019), 537–540
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P. A. Buikin, A. B. Ilyukhin, A. Y. Baranchikov, Kh. E. Yorov, V. Yu. Kotov, “The relationship between the crystal structure and optical properties for isomeric aminopyridinium iodobismuthates”, Mendeleev Commun., 28:5 (2018), 490–492
Sergey A. Adonin, Igor D. Gorokh, Pavel A. Abramov, Alexander S. Novikov, Ilya V. Korolkov, Maxim N. Sokolov, Vladimir P. Fedin, “Chlorobismuthates Trapping Dibromine: Formation of Two‐Dimensional Supramolecular Polyhalide Networks with Br2 Linkers”, Eur J Inorg Chem, 2017:42 (2017), 4925