Abstract:
Three phosphines bearing halodifluoromethyl group were obtained starting from chlorodiphenylphosphine. Silicon reagents Me3SiCF2X (X=Cl, Br) were used to install chloroor bromodifluoromethyl group to the phosphorus atom. Iododifluoromethyl-substituted phosphine was prepared by bromine/iodine exchange.
Document Type:
Article
Language: English
Citation:
R. O. Iakovenko, A. D. Dilman, “Synthesis of halodifluoromethyl-substituted phosphines”, Mendeleev Commun., 28:4 (2018), 396–397
Linking options:
https://www.mathnet.ru/eng/mendc1778
https://www.mathnet.ru/eng/mendc/v28/i4/p396
This publication is cited in the following 3 articles:
Alexey L. Trifonov, Alexander D. Dilman, “gem‐Difluoroolefination of Amides”, Chemistry A European J, 29:70 (2023)
Xanath Ispizua-Rodriguez, Colby Barrett, Vinayak Krishamurti, G.K. Surya Prakash, The Curious World of Fluorinated Molecules, 2021, 117
Yulia S. Kudyakova, Aleksandra Ya. Onoprienko, Pavel A. Slepukhin, Yanina V. Burgart, Victor I. Saloutin, Denis N. Bazhin, “Fluorine-Containing Furan-3(2N)-Ones in Reactions with Binucleophiles: CF3vs C2F5”, Chem Heterocycl Comp, 55:6 (2019), 517