Abstract:
The first examples of phosphorus-containing analogues of natural alkaloids, convolutamydines, have been obtained by aldol condensation of 4-[dialkyl(diphenyl)phosphoryl]-4-methylpentan-2-one with isatin. An unusually facile reversible process of dehydration–hydration of these phosphorus-containing hydroxy indoles has been discovered.
Document Type:
Article
Language: English
Citation:
D. A. Tatarinov, V. I. Osipova, A. V. Bogdanov, R. R. Fayzullin, V. F. Mironov, “3-(4-Phosphoryl-4-methyl-2-oxopentyl)-3-hydroxyindolin-2-ones, the first phosphorus analogues of natural convolutamydines”, Mendeleev Commun., 28:3 (2018), 292–294
Linking options:
https://www.mathnet.ru/eng/mendc1742
https://www.mathnet.ru/eng/mendc/v28/i3/p292
This publication is cited in the following 1 articles:
G. A. Chesnokov, A. A. Ageshina, A. V. Maryanova, S. A. Rzhevskiy, P. S. Gribanov, M. A. Topchiy, M. S. Nechaev, A. F. Asachenko, “Nitromethane as a reagent for the synthesis of 3-nitroindoles from 2-haloarylamine derivatives”, Russ Chem Bull, 69:12 (2020), 2370