Abstract:
Complex salt [(C5H5)Fe(C6H6)]3[Fe(CN)6] was synthesized and studied by X-ray diffraction. This salt was transformed into Prussian blue pigment upon the irradiation by visible light, which makes this reaction applicable to a photocopying (cyanotype) process.
Citation:
D. S. Perekalin, D. S. Shved, Yu. V. Nelyubina, “Organometallic cyanotype: formation of Prussian blue by a photochemical decomposition of the arene iron complex”, Mendeleev Commun., 29:1 (2019), 71–73
Linking options:
https://www.mathnet.ru/eng/mendc1426
https://www.mathnet.ru/eng/mendc/v29/i1/p71
This publication is cited in the following 5 articles:
Alexey S. Sokolov, Victoria A. Korabelnikova, Valentine P. Ananikov, Dmitrii A. Michurov, Vladimir I. Lozinsky, Dmitry S. Perekalin, “Photochemically induced formation of adhesive hydrogels from sodium alginate, acrylamide, and iron sandwich complexes”, Chem. Commun., 59:70 (2023), 10532
Parisa Gholamirad, Morteza Rouhani, “DFT study about the effects of BX3 (X = H, F, Cl and Br) derivatives on the C–H acidity enhancement”, MGC, 21:1 (2022), 29
Alexey S. Sokolov, Alexander V. Polezhaev, Yulia V. Nelyubina, Dmitry S. Perekalin, “Generation of Cyclopentadiene for Diels–Alder Reactions by Visible‐Light Irradiation of Iron Sandwich Complexes”, Helvetica Chimica Acta, 105:4 (2022)
Alexander Kraft, “Some considerations on the structure, composition, and properties of Prussian blue: a contribution to the current discussion”, Ionics, 27:6 (2021), 2289
Andrei M. Shved, Petr A. Zhmurov, Evgenii I. Gutsul, Dmitry S. Perekalin, “Patterning of various materials by the photochemical reaction of [(C5H5)Fe(C6H6)]+ complex with salicylate dyes”, New J. Chem., 44:42 (2020), 18157
Contact us: