This article is cited in 3 scientific papers (total in 3 papers)
Communications
Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement
Abstract:
The use of improved protocol for the reaction of rhodium acetylacetonate complexes (diene)RhAcac [diene is 1,5-cyclooctadiene or norbornadiene] with exo-nido-ruthenacarboranes 5,6,10-[RuCl(PPh3)2]-5,6,10-(μ-H)3-10-H-7,8-R2-7,8-C2B8H6 (R = H or Me) allowed us to synthesize three new binuclear complexes, wherein the ruthenium atom preserved exo-position and the rhodium-containing moiety coordinated to the open pentagonal face of exo-nido-complex. In addition, one known bimetallacarborane was also prepared for the evaluation of synthetic efficiency of the new procedure.
Citation:
D. I. D'yachikhin, A. Yu. Kostyukovich, I. A. Godovikov, A. P. Molotkov, E. V. Balagurova, I. T. Chizhevsky, “Modified synthesis of Ru–Rh heterobimetallic metallacarboranes based on ruthenium exo-nido complexes and not accompanied by exo-nido → closo rearrangement”, Mendeleev Commun., 29:1 (2019), 69–70
Linking options:
https://www.mathnet.ru/eng/mendc1425
https://www.mathnet.ru/eng/mendc/v29/i1/p69
This publication is cited in the following 3 articles:
A. M. Zimina, T. V. Kolpakova, S. A. Anufriev, E. I. Zueva, N. V. Somov, I. B. Sivaev, I. D. Grishin, “New 5-n-C4H9-C2B9-Carborane Ligand and Its Ruthenium Complexes”, Koordinacionnaâ himiâ, 49:6 (2023), 323
A. M. Zimina, T. V. Kolpakova, S. A. Anufriev, E. I. Zueva, N. V. Somov, I. B. Sivaev, I. D. Grishin, “New 5-n-C4H9-C2B9-Carborane Ligand and Its Ruthenium Complexes”, Russ J Coord Chem, 49:6 (2023), 329
I. D. Grishin, N. A. Knyazeva, A. M. Penkal', “Novel ruthenium(ii) and (iii) carborane complexes with diphosphine ligands and their application in radical polymerization”, Russ Chem Bull, 69:8 (2020), 1520
Contact us: