V. V. Lukov, A. A. Tsaturyan, Yu. P. Tupolova, S. I. Levchenkov, V. G. Vlasenko, L. D. Popov, I. V. Pankov, J. C. Poler, “Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol”, Mendeleev Commun., 29:1 (2019), 43

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Mendeleev Communications, 2019, Volume 29, Issue 1, Pages 43–46
DOI: https://doi.org/10.1016/j.mencom.2019.01.013 (Mi mendc1415)

This article is cited in 4 scientific papers (total in 4 papers)

Communications

Crystal structure and nontrivial magnetic properties of Cu^II binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol

V. V. Lukov^a, A. A. Tsaturyan^b, Yu. P. Tupolova^a, S. I. Levchenkov^ac, V. G. Vlasenko^d, L. D. Popov^a, I. V. Pankov^a, J. C. Poler^e

^a Department of Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^b Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
^c Southern Scientific Center of the Russian Academy of Sciences, Rostov-on-Don, Russian Federation
^d Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russian Federation
^e Department of Chemistry, University of North Carolina at Charlotte, Charlotte, USA

Full-text PDF (550 kB) Citations (4)

DOI: https://doi.org/10.1016/j.mencom.2019.01.013

Graphic abstract: Crystal structure and nontrivial magnetic properties of Cu<sup>II</sup> binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol

Abstract: The new complex [Cu₂(H₂L)Cl₃] with axial chloride ions coordination based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol was obtained and its crystal structure was determined. Magnetic studies revealed the presence of antiferromagnetic exchange interaction of −193 cm⁻¹ that is extremely high for such type of complexes. The quantum chemical calculation of 2J value has perfectly matched an experiment.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(986.3 Kb)

Citation: V. V. Lukov, A. A. Tsaturyan, Yu. P. Tupolova, S. I. Levchenkov, V. G. Vlasenko, L. D. Popov, I. V. Pankov, J. C. Poler, “Crystal structure and nontrivial magnetic properties of Cu^II binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol”, Mendeleev Commun., 29:1 (2019), 43–46

Linking options:

https://www.mathnet.ru/eng/mendc1415

https://www.mathnet.ru/eng/mendc/v29/i1/p43

This publication is cited in the following 4 articles:

Yu. P. Tupolova, D. V. Korchagin, V. E. Lebedev, L. D. Popov, G. V. Shilov, I. N. Shcherbakov, V. A. Chetverikova, S. M. Aldoshin, “Unsymmetrical Structure of the Co(III) Complex with Bisheteroarylhydrazone as Hydrazone and Quinolone Tautomers Stabilized by Hydrogen Bond”, Russ J Coord Chem, 48:6 (2022), 362
A. S. Burlov, V. G. Vlasenko, B. V. Chal'tsev, Yu. V. Koshchienko, S. I. Levchenkov, “Metal Complexes of Aroyl(acyl)benzoylhydrazones of Aromatic Aldehydes and Ketones: Coordination Modes and Properties”, Russ J Coord Chem, 47:7 (2021), 439
Konstantin P. Trainov, Olga G. Chechekina, Rinat F. Salikov, Dmitry N. Platonov, Yury V. Tomilov, “Electron deficient cyclopentadienolate in the synthesis of chromophores with mono- and poly-cyclic hydrazonocyclopentadiene acceptor moieties”, Dyes and Pigments, 187 (2021), 109132
Vladimir V. Lukov, Arshak A. Tsaturyan, Yulia P. Tupolova, Ilia V. Pankov, Leonid D. Popov, Nikolay N. Efimov, Konstantin B. Gishko, Vera A. Chetverikova, Igor N. Shcherbakov, “Determination of structures of Cu(II) and Ni(II) complexes based on 4-methyl-2,6-bis{[2-(4,6-dimethylpyrimidin-2-yl)-hydrazono]methyl}phenol by combine experimental and theoretical approaches”, Journal of Molecular Structure, 1199 (2020), 126952

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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