Abstract:
The title complexes were prepared, and their redox and catalytic properties in hydrogen evolution reaction were examined. The catalytic current increases in the presence of a proton source near the potential of the nickel(I/0) couple for a mixture of nickel(II) complexes with different ligands. Moreover, the catalytic activity of mixed-ligand complexes in the hydrogen evolution reaction was higher than that of a bis-chelated diphosphine nickel(II) complex.
Citation:
V. V. Khrizanforova, R. R. Fayzullin, E. I. Musina, A. A. Karasik, Yu. H. Budnikova, “Electrochemical and catalytic properties of nickel(II) complexes with bis(imino)acenaphthene and diazadiphosphacyclooctane ligands”, Mendeleev Commun., 30:3 (2020), 302–304
Linking options:
https://www.mathnet.ru/eng/mendc1177
https://www.mathnet.ru/eng/mendc/v30/i3/p302
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Eric S. Wiedner, Aaron M. Appel, Simone Raugei, Wendy J. Shaw, R. Morris Bullock, “Molecular Catalysts with Diphosphine Ligands Containing Pendant Amines”, Chem. Rev., 122:14 (2022), 12427
Renat R. Nazmutdinov, Yulia B. Dudkina, Tamara T. Zinkicheva, Yulia H. Budnikova, Michael Probst, “Ligand and solvent effects on the kinetics of the electrochemical reduction of Ni(II) complexes: Experiment and quantum chemical modeling”, Electrochimica Acta, 395 (2021), 139138
I. V. Nazarov, E. V. Bermesheva, K. V. Potapov, Z. B. Khesina, M. M. Ilyin, E. K. Melnikova, M. V. Bermeshev, “Palladium complex with tetrahydronaphthyl-substituted diimine ligand as a catalyst for polymerization of norbornenes and diazoacetates”, Mendeleev Commun., 31:5 (2021), 690–692
Yulia H. Budnikova, Vera V. Khrizanforova, “Synthetic models of hydrogenases based on framework structures containing coordinating P, N-atoms as hydrogen energy electrocatalysts – from molecules to materials”, Pure and Applied Chemistry, 92:8 (2020), 1305
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