Abstract:
The structural changes in BaTiO3 nanocrystal powder and tablets have been probed via X-ray diffraction, scanning electron and transmission microscopy, and differential calorimetry after successive hightemperature annealing in air. It is shown that, beginning with the annealing temperature of 1200∘C, significant amount of the Ba2TiO4 phase forms in the tablets together with the BaTiO3 phase. This phase is equilibrium one; it practically vanishes when the annealing temperature decreases to 700–600∘C; and this phase practically restored to the initial state when the annealing temperature is again increased to 1200∘C. Annealing the powders causes no formation of new phases, but an increase in their crystallite sizes. A probable reason of the emergence of Ba2TiO4 phase in tablets and its absence in free powder is discussed, as well.
Citation:
I. M. Shmyt'ko, D. D. Frolov, A. S. Aronin, G. R. Ganeeva, V. V. Kedrov, “Formation of new structural states in compressed BaTiO3 nanopowders”, Fizika Tverdogo Tela, 59:6 (2017), 1173–1182; Phys. Solid State, 59:6 (2017), 1196–1205
\Bibitem{ShmFroAro17}
\by I.~M.~Shmyt'ko, D.~D.~Frolov, A.~S.~Aronin, G.~R.~Ganeeva, V.~V.~Kedrov
\paper Formation of new structural states in compressed BaTiO$_{3}$ nanopowders
\jour Fizika Tverdogo Tela
\yr 2017
\vol 59
\issue 6
\pages 1173--1182
\mathnet{http://mi.mathnet.ru/ftt9557}
\crossref{https://doi.org/10.21883/FTT.2017.06.44490.230}
\elib{https://elibrary.ru/item.asp?id=29405125}
\transl
\jour Phys. Solid State
\yr 2017
\vol 59
\issue 6
\pages 1196--1205
\crossref{https://doi.org/10.1134/S1063783417060269}
Linking options:
https://www.mathnet.ru/eng/ftt9557
https://www.mathnet.ru/eng/ftt/v59/i6/p1173
This publication is cited in the following 3 articles:
Saiwei Luan, Pengfei Wang, Lei Zhang, Yanmei He, Xiong Huang, Gang Jian, Cuicui Liu, Shuhui Yu, Rong Sun, Xiuhua Cao, Zhenxiao Fu, “Atmospherically hydrothermal assisted solid-state reaction synthesis of ultrafine BaTiO3 powder with high tetragonality”, J Electroceram, 50:4 (2023), 97
I. M. Shmyt'ko, “Study of changes in the crystal structure of BaTiO<sub>3</sub> under the effect of X-ray radiation”, Zavod. lab., Diagn. mater., 86:11 (2020), 36
Ming Li, Lulu Gu, Tao Li, Shiji Hao, Furui Tan, Deliang Chen, Deliang Zhu, Yongjun Xu, Chenghua Sun, Zhenyu Yang, “TiO2-Seeded Hydrothermal Growth of Spherical BaTiO3 Nanocrystals for Capacitor Energy-Storage Application”, Crystals, 10:3 (2020), 202