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Fizika Tverdogo Tela, 2017, Volume 59, Issue 10, Pages 2056–2062
DOI: https://doi.org/10.21883/FTT.2017.10.44980.085
(Mi ftt9443)
 

This article is cited in 1 scientific paper (total in 1 paper)

Atomic clusters

On magnetism of nickel clusters in nanoporous carbon

A. M. Danishevskiia, B. D. Shaninab, A. Yu. Rogacheva, V. V. Sokolova, A. E. Kalmykova, R. N. Kyutta, S. K. Gordeevc

a Ioffe Institute, St. Petersburg
b Institute of Semiconductor Physics NAS, Kiev, Ukraine
c Central Research Institute of Materials, St. Petersburg
Abstract: The structural and magnetometric characteristics of a nanoporous carbon with nickel clusters in nanopores have been studied. The main attention is focused on the fact of substantial decrease in the nickel magnetization as nickel has a close contact to carbon as compared to similar parameter of free nickel microparticles with almost the same sizes. A theoretical model of a periodic cluster consisting of 16 carbon atoms and one nickel atom in a micropore surrounded by carbon atoms has been built. The electron density in such a cluster and its magnetism were found by computer calculations. It is shown that the magnetic moment of a nickel atom in the cluster is substantially smaller than that of a free nickel atom. Based on the results, it is concluded that the decrease in the magnetization of nickel clusters in the carbon environment observed experimentally is due to the adsorption interaction of the nickel and carbon electron subsystems.
Received: 22.03.2017
English version:
Physics of the Solid State, 2017, Volume 59, Issue 10, Pages 2082–2088
DOI: https://doi.org/10.1134/S1063783417100110
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: A. M. Danishevskii, B. D. Shanina, A. Yu. Rogachev, V. V. Sokolov, A. E. Kalmykov, R. N. Kyutt, S. K. Gordeev, “On magnetism of nickel clusters in nanoporous carbon”, Fizika Tverdogo Tela, 59:10 (2017), 2056–2062; Phys. Solid State, 59:10 (2017), 2082–2088
Citation in format AMSBIB
\Bibitem{DanShaRog17}
\by A.~M.~Danishevskii, B.~D.~Shanina, A.~Yu.~Rogachev, V.~V.~Sokolov, A.~E.~Kalmykov, R.~N.~Kyutt, S.~K.~Gordeev
\paper On magnetism of nickel clusters in nanoporous carbon
\jour Fizika Tverdogo Tela
\yr 2017
\vol 59
\issue 10
\pages 2056--2062
\mathnet{http://mi.mathnet.ru/ftt9443}
\crossref{https://doi.org/10.21883/FTT.2017.10.44980.085}
\elib{https://elibrary.ru/item.asp?id=30108742}
\transl
\jour Phys. Solid State
\yr 2017
\vol 59
\issue 10
\pages 2082--2088
\crossref{https://doi.org/10.1134/S1063783417100110}
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  • https://www.mathnet.ru/eng/ftt/v59/i10/p2056
  • This publication is cited in the following 1 articles:
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
    Fizika Tverdogo Tela Fizika Tverdogo Tela
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