Abstract:
A pyrolyzate of iron phthalocyanine is studied by Mössbauer spectroscopy and transmission electron microscopy. The phase composition and magnetic state were found for pyrolysis products (α-Fe, γ-Fe, Fe3C, and magnetite). Morphological features of carbon and iron-containing phases (metal particles of various shapes and sizes, as well as carbon nanotubes, carbon hollow nanopolihedra, and nongraphitized carbon) are determined. The morphology and structure of iron phthalocyanine pyrolyzates and diphthalocyanines of rare-earth elements are analyzed.
Citation:
V. S. Kozlov, V. G. Semenov, K. G. Karateeva, V. Yu. Bairamukov, “A study of iron phthalocyanine pyrolyzate with Mössbauer spectroscopy and transmission electron microscopy”, Fizika Tverdogo Tela, 60:5 (2018), 1018–1023; Phys. Solid State, 60:5 (2018), 1035–1040
\Bibitem{KozSemKar18}
\by V.~S.~Kozlov, V.~G.~Semenov, K.~G.~Karateeva, V.~Yu.~Bairamukov
\paper A study of iron phthalocyanine pyrolyzate with M\"ossbauer spectroscopy and transmission electron microscopy
\jour Fizika Tverdogo Tela
\yr 2018
\vol 60
\issue 5
\pages 1018--1023
\mathnet{http://mi.mathnet.ru/ftt9217}
\crossref{https://doi.org/10.21883/FTT.2018.05.45806.307}
\elib{https://elibrary.ru/item.asp?id=32739898}
\transl
\jour Phys. Solid State
\yr 2018
\vol 60
\issue 5
\pages 1035--1040
\crossref{https://doi.org/10.1134/S106378341805013X}
Linking options:
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This publication is cited in the following 7 articles:
V. S. Kozlov, V. G. Semenov, A. A. Bykov, V. Yu. Bairamukov, “Localization and Charge State of Metal Ions in Carbon Nanostructures of Europium Bis-Phthalocyanine Pyrolysed Derivatives”, Tech. Phys., 69:7 (2024), 2007
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Davide Menga, Ana Guilherme Buzanich, Friedrich Wagner, Tim‐Patrick Fellinger, “Bestimmung der spezifischen Aktivität von M-N-Cs und die intrinsische Aktivität von tetrapyrrolischen FeN4‐Zentren in der Sauerstoffreduktionsreaktion”, Angewandte Chemie, 134:50 (2022)
V. P. Sedov, A. A. Borisenkova, S. V. Fomin, M. V. Suyasova, D. N. Orlova, N. S. Fokin, A. S. Krivorotov, “Processing of Metal-Containing Electroplating Slimes into Mixed Water-Soluble Metal–Carbon Structures”, Russ J Appl Chem, 94:5 (2021), 560
Xiaojiang Wang, Tianlong Zheng, Yizhao Tang, Xiaoyu Li, Alexandre I. Rykov, Xuning Li, Junhu Wang, Qinggang He, Jun Cheng, Xue Zhang, “The Effect of Tuning the Coordination Sphere of Iron Complexes for the Oxygen Reduction Reaction in Acidic Media”, J. Electrochem. Soc., 168:4 (2021), 044506
V. Yu. Bairamukov, A. I. Kuklin, D. N. Orlova, V. T. Lebedev, “Structure of Yttrium Bis-Phthalocyanine Pyrolyzed Derivatives”, J. Synch. Investig., 13:5 (2019), 793
Xue Zhang, Chi Chen, Jiao Dong, Rui‐Xiang Wang, Qiang Wang, Zhi‐You Zhou, Shi‐Gang Sun, “Comparative Study of the Oxygen Reduction Reaction on Pyrolyzed FePc in Acidic and Alkaline Media”, ChemElectroChem, 5:24 (2018), 3946