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This article is cited in 3 scientific papers (total in 3 papers)
International Conference ''Mechanisms and Nonlinear Problems of Nucleation, Growth of Crystals and Thin Films'' dedicated to the memory of the outstanding theoretical physicist Professor V.V. Slezov (Proceedings) St. Petersburg, July 1-5, 2019
Phase transitions
On the probability-free mechanism of macroscopic irreversibility and microscopic foundation of thermodynamics
A. Yu. Zakharov Yaroslav-the-Wise Novgorod State University, Veliky Novgorod, Russia
Abstract:
It is shown that retardation of the interactions between particles leads to the non-existence of potential energy and the Hamiltonian of the particle system. This leads to the impossibility of calculating the thermodynamic functions of the system by the methods of statistical mechanics. The dynamics of a system of particles with delayed interactions is described by a system of functional differential equations. The qualitative properties of the solutions of this system of equations are investigated. The solutions are irreversible with respect to time reversal. The number of degrees of freedom of even a finite system with retarded interactions is infinite.
Keywords:
thermodynamics, many particle systems.
Received: 16.07.2019 Revised: 16.07.2019 Accepted: 25.07.2019
Citation:
A. Yu. Zakharov, “On the probability-free mechanism of macroscopic irreversibility and microscopic foundation of thermodynamics”, Fizika Tverdogo Tela, 61:12 (2019), 2430; Phys. Solid State, 61:12 (2019), 2442–2445
Linking options:
https://www.mathnet.ru/eng/ftt8585 https://www.mathnet.ru/eng/ftt/v61/i12/p2430
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