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This article is cited in 4 scientific papers (total in 4 papers)
Semiconductors
Structure and electrical conductivity of the perovskites Pr$_{1-x}$Sr$_{x}$MnO$_{3}$ ($x$ = 0; 0.15; 0.25)
L. B. Vedmid'ab, O. M. Fedorovaa, V. B. Balakirevac, V. A. Vorotnikovbc, V. F. Balakireva a Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, Ekaterinburg, Russia
b Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg, Russia
c Institute of High-Temperature Electrochemistry, RAS, Ekaterinburg, Russia
Abstract:
Pr$_{1-x}$Sr$_{x}$MnO$_{3}$ manganites ($x$ = 0; 0.15; 0.25) were synthesized by the solid-phase method at a temperature of 1250$^{\circ}$C and have an orthorhombic perovskite-like structure (space group $Pbnm$). A comprehensive study of the effect of praseodymium substitution with strontium on the temperature features of the transformation of the crystal structure of the studied perovskites was performed using high-temperature radiography and differential thermal analysis. It was determined that the temperature of the Jahn-Тeller effect significantly decreases with the introduction of strontium. It is established that all samples have a semiconductor character of conductivity. Strontium doping significantly increases the electrical conductivity of praseodymium manganites, especially at temperatures below 450$^{\circ}$C.
Keywords:
strontium, rare earth element manganites, perovskites, Jahn–Тeller effect, electrical conductivity.
Received: 10.12.2020 Revised: 17.12.2020 Accepted: 17.12.2020
Citation:
L. B. Vedmid', O. M. Fedorova, V. B. Balakireva, V. A. Vorotnikov, V. F. Balakirev, “Structure and electrical conductivity of the perovskites Pr$_{1-x}$Sr$_{x}$MnO$_{3}$ ($x$ = 0; 0.15; 0.25)”, Fizika Tverdogo Tela, 63:4 (2021), 465–470; Phys. Solid State, 63:4 (2021), 660–665
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https://www.mathnet.ru/eng/ftt8145 https://www.mathnet.ru/eng/ftt/v63/i4/p465
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