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Fizika Tverdogo Tela, 2021, Volume 63, Issue 4, Pages 465–470
DOI: https://doi.org/10.21883/FTT.2021.04.50710.258
(Mi ftt8145)
 

This article is cited in 4 scientific papers (total in 4 papers)

Semiconductors

Structure and electrical conductivity of the perovskites Pr$_{1-x}$Sr$_{x}$MnO$_{3}$ ($x$ = 0; 0.15; 0.25)

L. B. Vedmid'ab, O. M. Fedorovaa, V. B. Balakirevac, V. A. Vorotnikovbc, V. F. Balakireva

a Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, Ekaterinburg, Russia
b Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg, Russia
c Institute of High-Temperature Electrochemistry, RAS, Ekaterinburg, Russia
Abstract: Pr$_{1-x}$Sr$_{x}$MnO$_{3}$ manganites ($x$ = 0; 0.15; 0.25) were synthesized by the solid-phase method at a temperature of 1250$^{\circ}$C and have an orthorhombic perovskite-like structure (space group $Pbnm$). A comprehensive study of the effect of praseodymium substitution with strontium on the temperature features of the transformation of the crystal structure of the studied perovskites was performed using high-temperature radiography and differential thermal analysis. It was determined that the temperature of the Jahn-Тeller effect significantly decreases with the introduction of strontium. It is established that all samples have a semiconductor character of conductivity. Strontium doping significantly increases the electrical conductivity of praseodymium manganites, especially at temperatures below 450$^{\circ}$C.
Keywords: strontium, rare earth element manganites, perovskites, Jahn–Тeller effect, electrical conductivity.
Funding agency Grant number
Ministry of Education and Science of the Russian Federation
This work was supported within a state assignment to the Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, and performed using the facilities of the Center for Collective Use “Ural-M”.
Received: 10.12.2020
Revised: 17.12.2020
Accepted: 17.12.2020
English version:
Physics of the Solid State, 2021, Volume 63, Issue 4, Pages 660–665
DOI: https://doi.org/10.1134/S1063783421040235
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: L. B. Vedmid', O. M. Fedorova, V. B. Balakireva, V. A. Vorotnikov, V. F. Balakirev, “Structure and electrical conductivity of the perovskites Pr$_{1-x}$Sr$_{x}$MnO$_{3}$ ($x$ = 0; 0.15; 0.25)”, Fizika Tverdogo Tela, 63:4 (2021), 465–470; Phys. Solid State, 63:4 (2021), 660–665
Citation in format AMSBIB
\Bibitem{VedFedBal21}
\by L.~B.~Vedmid', O.~M.~Fedorova, V.~B.~Balakireva, V.~A.~Vorotnikov, V.~F.~Balakirev
\paper Structure and electrical conductivity of the perovskites Pr$_{1-x}$Sr$_{x}$MnO$_{3}$ ($x$ = 0; 0.15; 0.25)
\jour Fizika Tverdogo Tela
\yr 2021
\vol 63
\issue 4
\pages 465--470
\mathnet{http://mi.mathnet.ru/ftt8145}
\crossref{https://doi.org/10.21883/FTT.2021.04.50710.258}
\elib{https://elibrary.ru/item.asp?id=46345490}
\transl
\jour Phys. Solid State
\yr 2021
\vol 63
\issue 4
\pages 660--665
\crossref{https://doi.org/10.1134/S1063783421040235}
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  • This publication is cited in the following 4 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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    Fizika Tverdogo Tela Fizika Tverdogo Tela
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