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This article is cited in 2 scientific papers (total in 2 papers)
Semiconductors
Heat capacity and thermodynamic functions of GdGaTi$_{2}$O$_{7}$ in the temperature range of 320–1000 K
L. T. Denisovaa, M. S. Molokeevab, L. G. Chumilinaa, V. V. Ryabovc, V. M. Denisova a Siberian Federal University, Krasnoyarsk, Russia
b L. V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia
c Institute of Metallurgy, Ural Division of the Russian Academy of Sciences, Ekaterinburg, Russia
Abstract:
Titanate GdGaTi$_{2}$O$_{7}$ has been obtained from the initial oxides Gd$_{2}$O$_{3}$, Ga$_{2}$O$_{3}$, and TiO$_{2}$ by the solid-state synthesis via annealing in air at temperatures of 1273 and 1573 K. The crystal structure of the titanate has been refined by X-ray diffraction. The high-temperature (320–1000 K) heat capacity of the compound has been measured by differential scanning calorimetry. Based on the experimental dependence $C_p = f(T)$, the main thermodynamic functions of the titanate have been calculated.
Keywords:
rare-earth titanates, solid-state synthesis, high-temperature heat capacity, thermodynamic functions.
Received: 16.12.2020 Revised: 16.12.2020 Accepted: 18.12.2020
Citation:
L. T. Denisova, M. S. Molokeev, L. G. Chumilina, V. V. Ryabov, V. M. Denisov, “Heat capacity and thermodynamic functions of GdGaTi$_{2}$O$_{7}$ in the temperature range of 320–1000 K”, Fizika Tverdogo Tela, 63:4 (2021), 471–474; Phys. Solid State, 63:4 (2021), 534–537
Linking options:
https://www.mathnet.ru/eng/ftt8146 https://www.mathnet.ru/eng/ftt/v63/i4/p471
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