Computational aspects of $^{19}\mathrm{F}$ NMR

This review covers most recent advances in computation of $^{19}\mathrm{F}$ NMR chemical shifts and spin–spin coupling constants involving $^{19}\mathrm{F}$ nucleus calculated at different levels of theory. It deals mainly with electronic and stereochemical effects influencing these parameters, with a special emphasis on practical applications of such calculations. For $^{19}\mathrm{F}$ NMR chemical shifts, a good deal of attention is focused on less common solid state studies, in addition to much more popular liquid state data. For spin–spin coupling constants, the main interest is concentrated on the most popular $^{19}\mathrm{F}$–$^1\mathrm{H}$, $^{19}\mathrm{F}$–$^{13}\mathrm{C}$ and $^{19}\mathrm{F}$– $^{19}\mathrm{F}$ couplings providing marked stereochemical behaviour.
The bibliography includes 149 references.