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Эта публикация цитируется в 20 научных статьях (всего в 20 статьях)
Cyclization of ortho-ethynylbiaryls as an emerging versatile tool for the construction of polycyclic arenes
Alena S. Pankova, Aleksandr N. Shestakov, Mikhail A. Kuznetsov Institute of Chemistry, Saint Petersburg State University
Аннотация:
Cyclization and cycloisomerization of ortho-aryl(ethynyl)arenes provide an easy direct access to fused polycyclic aromatic carbo- and heterocycles. This methodology has demonstrated an impressive progress in the recent years. The goal of this review is to give a comprehensive outlook on the synthetic potential, scope, limitations, and mechanistic aspects of the cyclization reactions. The material is arranged according to the activation method that can be used to induce cyclization: pyrolysis, metal catalysis, electrophilic activation, radical induction, base catalysis. Particular attention is paid to the specificity of ortho-ethynylbiaryls with a heterocyclic central core. The bibliography includes 257 references.
Поступила в редакцию: 08.10.2018
Образец цитирования:
Alena S. Pankova, Aleksandr N. Shestakov, Mikhail A. Kuznetsov, “Cyclization of ortho-ethynylbiaryls as an emerging versatile tool for the construction of polycyclic arenes”, Усп. хим., 88:6 (2019), 594–643; Russian Chem. Reviews, 88:6 (2019), 594–643
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/rcr4255 https://www.mathnet.ru/rus/rcr/v88/i6/p594
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