Аннотация:
Control of atomic and molecular scale systems with quantum dynamics
attracts nowadays high interest due to rich mathematical theory
and various existing and prospective applications in physics, chemistry, and
molecular biology including laser-assisted control of
chemical reactions, quantum metrology, quantum optics, etc. Modern
quantum technologies which might revolutionize our society like
semiconductor revolution did in the second half of the twentieth
century, are based on methods of quantum control [1–4].
Mathematical formulation of a quantum control problem included description of
state space of the system, the dynamical equation, and specification of
the target objective functional. The dynamics of the controlled quantum system
is governed either by Schrödinger equation if the system is closed, that is,
isolated from the environment, or by a master-equation if the system is open,
that is, interacts with an environment. In both cases the evolution equation
includes the control function which can be shaped laser field, spectral density
of incoherent photons, or other external action. Objective functional can
describe probability of transition from one state to another, average value
of quantum observable, gate generation, etc. The goal of the optimal control is
to find such a control function which maximizes the objective functional.
In this talk we will discuss recent progress in two very important and
interesting topics in
modern quantum control—controllability of open quantum systems and the
analysis of quantum control landscapes.
Controllability of quantum systems deals with finding methods for transferring
arbitrary initial states into arbitrary final states with admissible controls.
We will discuss a method for a controlled engineering of arbitrary quantum
states (density matrices) of $n$-level quantum systems which might be used for
prospective quantum computing with mixed states [5].
Analysis of the control landscape, that is, graph of the objective functional,
deals with the analysis of local but not global extrema (traps) of the
objective functional. We will discuss the recent discovery of absence of
traps for two-level systems [6,7] which are important as representing qubit—a
basis building block for quantum computation, and for systems with
infinite-dimensional state space, namely, for transmission coefficient of a
quantum particle on the line passing through one-dimensional potential whose
shape is used as a control [5]. For the latter, we consider a quantum particle
of energy $E$ moving from the left in one dimensional potential $V(x)$ which is
assumed to have compact support. Probability for the
particle to appear far away on the right of the potential is the transmission
coefficient $T_E[V]$. The transmission coefficient is a functional of the
potential $V(x)$ and can be controlled by varying its shape. We show that
the only extrema of the transmission coefficient as a functional of the
potential $V$ are global maxima corresponding to full transmission [8]. This
result is of high mathematical importance as the first result
about absence of traps for quantum systems with infinite dimensional state space
and of high practical significance as it says that manipulating by
transmission coefficient is trap free.
C. Brif, R. Chakrabarti, H. Rabitz, Control of quantum phenomena, Advances in Chemical Physics, 148, eds. S. A. Rice and A. R. Dinner, Wiley, 2012
“Theo Murphy Meeting Issue “Principles and applications of quantum control engineering” organized and edited by John Gough”, Philosophical Transactions of the Royal Society, 370(1979) (2012)
K. W. Moore, A. Pechen, X.-J. Feng, J. Dominy, V. Beltrani, H. Rabitz, “Universal characteristics of chemical synthesis and property optimization”, Chemical Science, 2:3 (2011), 417–424
X.-J. Feng, A. Pechen, A. Jha, R. Wu, H. Rabitz, “Global optimality of fitness landscapes in evolution”, Chemical Science, 3:4 (2012), 900–906
A. Pechen, “Engineering arbitrary pure and mixed quantum states”, Phys. Rev. A, 84 (2011), 042106
A. Pechen, N. Il'in, “Trap-free manipulation in the Landau-Zener system”, Phys. Rev. A, 86 (2012), 052117
A. Pechen, N. Il'in, “Coherent control of a qubit is trap-free”, Proceedings of Steklov Mathematical Institute, 2014 (to appear)
A. N. Pechen, D. J. Tannor, “Control of quantum transmission is trap-free”, Canadian Journal of Chemistry, 92:2 (2014), 157–159