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CHEMISTRY AND MATERIAL SCIENCE
Role of carbon in the formation of the structure and magnetic properties of Ni-CN$_x$ nanoclusters under reactive magnetron deposition
R. V. Shalayev, V. N. Varyukhin, A. M. Prudnikov, A. I. Linnik, V. V. Syrotkin Donetsk Institute for Physics and Engineering named after A. A. Galkin,
R. Luxembourg str. 72, 83114, Donetsk, Ukraine
Аннотация:
Nanostructured hybrid Ni-CN$_x$ films were grown by magnetron sputtering of a composite graphite-nickel target. Atomic force microscopy showed the clustered nature of the films deposition on the substrate surface: a relatively high pressure in the low-temperature magnetron plasma made it possible to form the Ni@CN$_x$ nanoclusters type “core-shell”, where metallic nickel is the core and carbon nitride is the shell. When studying the role of carbon in the formation of the structure and properties of Ni@CN$_x$ nanoclusters, it was established that the saturation magnetization 4$\pi$M$_s$ of nanoclusters drops sharply with a carbon content above 30 at.%. The reason is the formation of an increasingly saturated solid solution of carbon in nickel. At a carbon concentrations above 38 at.%, amorphous Ni-CN$_x$ nanoclusters are formed in the magnetron plasma, which are deposited on the substrate. An increase in the substrate temperature leads to the crystallization of Ni atoms, and the C and N atoms are forced out onto the surface of the nickel core, forming an array of Ni-CN$_x$ elements.
Ключевые слова:
carbon nitride, nanoclusters, magnetron sputtering.
Поступила в редакцию: 03.11.2017 Исправленный вариант: 16.11.2017
Образец цитирования:
R. V. Shalayev, V. N. Varyukhin, A. M. Prudnikov, A. I. Linnik, V. V. Syrotkin, “Role of carbon in the formation of the structure and magnetic properties of Ni-CN$_x$ nanoclusters under reactive magnetron deposition”, Наносистемы: физика, химия, математика, 8:6 (2017), 804–808
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/nano106 https://www.mathnet.ru/rus/nano/v8/i6/p804
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