aSchool of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China bDivision of General Studies, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China
Аннотация:
Iron(III) nitrate-assisted cycloaddition of (phenylsulfonyl)ethene to arylacetylenes in the presence of KI affords 5-phenylsulfonyl-3-aroylisoxazolines whose treatment with K2CO3 provides 4,5-unsubstituted 3-aroylisoxazoles. Both synthetic steps can be performed in a one-pot manner.
Ключевые слова:
iron nitrate, nitration, alkynes, 1,3-dipolar cycloaddition, isoxazolines, isoxazoles.
Образец цитирования:
L. Wang, N. Zhang, “One-pot synthesis of 5-phenylsulfonyl-3-aroylisoxazolines and 3-aroylisoxazoles from alkynes and (phenylsulfonyl)ethene”, Mendeleev Commun., 31:3 (2021), 390–392