Аннотация:
Stoichiometry and stability of electron donor–acceptor complexes formed by dibenzothiophene and its alkylated derivatives with DDQ and TCNE in nonpolar organic solvents has been investigated. 4,6-Dimethyldibenzothiophene produces the most stable 1: 1 complex with DDQ in agreement with energy levels of the π-donors HOMOs and π-acceptors LUMOs calculated by DFT. The results make possible an employment of the complexes for multiplex determination of polycyclic aromatic pollutants using surface enhanced Raman spectroscopy.
Образец цитирования:
O. E. Eremina, M. V. Samodelova, M. V. Ferree, T. N. Shekhovtsova, I. A. Veselova, “Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes”, Mendeleev Commun., 31:3 (2021), 326–329
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc919
https://www.mathnet.ru/rus/mendc/v31/i3/p326
Эта публикация цитируется в следующих 2 статьяx:
Chandani Mathur, Raakhi Gupta, Raj K. Bansal, “Organic Donor‐Acceptor Complexes As Potential Semiconducting Materials”, Chemistry A European J, 30:23 (2024)
Olga E. Eremina, Olesya O. Kapitanova, Mariia V. Ferree, Irina A. Lemesh, Dmitry B. Eremin, Eugene A. Goodilin, Irina A. Veselova, “Ultrasensitive and multiplex SERS determination of anthropogenic phenols in oil fuel and environmental samples”, Environ. Sci.: Nano, 9:3 (2022), 964
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