Аннотация:
The reaction of the trinuclear copper(i) 3,5-bis(trifluoromethyl) pyrazolate with 2,2′-bipyridine on contact with air leads to the oxidation of Cu centers and affords trinuclear Cuii complex containing bridged pyrazolate OH anions and chelating bipy ligands. Carrying out the reaction in the presence of dppm prevents oxidation and gives dinuclear copper(i) complex with bridging dppm and pyrazolate ligands, and chelating bipy ligand. This complex exhibits red-orange phosphorescence originating from the 3MLbipyCT state.
Образец цитирования:
A. A. Titov, O. A. Filippov, A. F. Smol'yakov, A. A. Averin, E. S. Shubina, “New mix-ligand copper(i) and copper(ii) pyrazolate complexes with 2,2′-bipyridine”, Mendeleev Commun., 31:2 (2021), 170–172
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc868
https://www.mathnet.ru/rus/mendc/v31/i2/p170
Эта публикация цитируется в следующих 10 статьяx:
Marina A. Uvarova, Fedor M. Dolgushin, Konstantin A. Babeshkin, Nikolay N. Efimov, Natalia V. Gogoleva, Denis N. Nebykov, Anastasia V. Lagutina, Alexandr O. Panov, Vladimir M. Mokhov, Olga B. Bekker, Konstantin O. Titov, Irina A. Lutsenko, Igor L. Eremenko, “Versatile CoII and NiII mononuclear complexes with furoate/thiophencarboxylate anions and 3,5-dimethylpyrazole– Synthesis, structure, magnetic, catalytic and antimycobacterial properties”, Inorganica Chimica Acta, 575 (2025), 122445
Wen-Hui Jiang, Xiang-Ming Zeng, Minjian Wu, Lin Qin, Liao-Yuan Yao, Guo-Yu Yang, “Thermally Activated Delayed Fluorescence-Based Near-Infrared-II Luminescence and Controlled Size Growth of Silver Nanoclusters”, ACS Nano, 2025
Yan V. Demyanov, Irina Yu. Bagryanskaya, Marianna I. Rakhmanova, Alexander V. Artem'ev, “Bi- and tetranuclear Cu(I) complexes based on tris(6-methyl-2-pyridyl)phosphine: Synthesis and photophysical study”, Inorganic Chemistry Communications, 169 (2024), 113062
Guo-Quan Huang, Xu Chen, Ji Zheng, Dan Li, “The π-acidic coinage-metal cyclic trinuclear complexes with Lewis or π-bases and the relevant applications”, Journal of Organometallic Chemistry, 1006 (2024), 122980
Ya. V. Demyanov, I. Yu. Bagryanskaya, A. V. Artem'ev, “CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide”, Mendeleev Commun., 34:6 (2024), 812–814
M. A. Uvarova, S. E. Nefedov, “Influence of substituents in the pyrazole pre-ligands on their reaction products with (Phen)Pd(OAc)2”, Mendeleev Commun., 34:1 (2024), 54–56
M. A. Uvarova, M. A. Shmelev, S. E. Nefedov, “Heteroleptic Binuclear Pivalate-, Pyrazolate-Bridged Copper(II) Complexes with 1,10-Phenanthroline”, Russ J Coord Chem, 50:11 (2024), 1029
Ya. V. Demyanov, M. I. Rakhmanova, I. Yu. Bagryanskaya, A. V. Artem'ev, “Cu4I4-cubane cluster based on tris(p-anisyl)arsine: Synthesis, crystal structure and photophysical properties”, Mendeleev Commun., 33:4 (2023), 484–486
M. A. Uvarova, S. E. Nefedov, “Deprotonation of 3,5-Bis(trifluoromethyl)pyrazole in the Presence of [Phen2Co2(µ-OH2)(µ-OOCMe)2(OOCMe)2]”, Russ J Coord Chem, 48:12 (2022), 909
Ya. V. Demyanov, M. I. Rakhmanova, I. Yu. Bagryanskaya, A. V. Artem'ev, “1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties”, Mendeleev Commun., 32:5 (2022), 649–651
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