Аннотация:
New unsymmetrically substituted benzothiadiazoles were synthesized from 4,7-dibromo-2,1,3-benzothiadiazole via the sequence of Pd-catalyzed Suzuki and Buchwald–Hartwig cross-coupling reactions with 4-methoxyphenylboronic acid and heterocyclic amines, respectively. Based on initially performed photophysical study as well as DFT calculation, these compounds, in particular with dibenzoazepine core, can be selected as promising scaffolds for further fine-tuning of their properties to be used in optoelectronics including OLED technologies.
Образец цитирования:
P. S. Gribanov, D. A. Lypenko, A. V. Dmitriev, S. I. Pozin, M. A. Topchiy, A. F. Asachenko, D. A. Loginov, S. N. Osipov, “Synthesis and optical properties of novel unsymmetrically substituted benzothiadiazole-based luminophores”, Mendeleev Commun., 31:1 (2021), 33–35
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc825
https://www.mathnet.ru/rus/mendc/v31/i1/p33
Эта публикация цитируется в следующих 13 статьяx:
Xiaoyu Yin, Junrong Pu, Chen Ma, Yi Wu, Kunlun Wang, Yingliang Liu, Shaokui Cao, Shi-Jian Su, Shengang Xu, “Solution-processable benzothiadiazole/triphenylamine-based hybridized local and charge-transfer (HLCT) hyper-structured molecular red emitters for OLEDs”, J. Mater. Chem. C, 2025
Shipan Xu, Xuyang Du, Xiaolong Yang, Huaiteng Hang, Jun Xi, Guijiang Zhou, Yuanhui Sun, “Design of donor-acceptor-acceptor (D-A-A′)-type fluorescence emitters based on benzothiadiazole with the hybridized local and charge-transfer (HLCT) excited state feature for green to deep-red emitting OLEDs”, Organic Electronics, 137 (2025), 107182
Pavel S. Gribanov, Anna N. Philippova, Maxim A. Topchiy, Dmitry A. Lypenko, Artem V. Dmitriev, Sergey D. Tokarev, Alexander F. Smol'yakov, Alexey N. Rodionov, Andrey F. Asachenko, Sergey N. Osipov, “Synthesis of 5-(Aryl)amino-1,2,3-triazole-containing 2,1,3-Benzothiadiazoles via Azide–Nitrile Cycloaddition Followed by Buchwald–Hartwig Reaction”, Molecules, 29:9 (2024), 2151
Pavel S. Gribanov, Daria V. Vorobyeva, Dmitry A. Loginov, Sergey D. Tokarev, Anna N. Philippova, Alexander F. Smol'yakov, Salekh M. Masoud, Pavel N. Solyev, Sergey N. Osipov, “Synthesis of Isoquinoline‐Containing 5,6‐Dicyano‐2,1,3‐Benzothiadiazoles: Unusual Heterocyclization into Dibenzo‐1,6‐Naphthyridine Framework”, Asian J Org Chem, 2024
E. S. Fedina, M. A. Arsenov, K. L. Isakovskaya, D. V. Muratov, D. A. Loginov, “Synthesis and photophysical activity of 6-substituted isocoumarins”, Mendeleev Commun., 34:1 (2024), 107–109
P. S. Gribanov, D. A. Loginov, D. A. Lypenko, A. V. Dmitriev, S. D. Tokarev, A. E. Aleksandrov, A. R. Tameev, A. Yu. Chernyadyev, S. N. Osipov, “New electron-deficient 2,1,3-benzothiadiazole-cored donor–acceptor compounds: Synthesis, photophysical and electroluminescent properties”, Mendeleev Commun., 33:5 (2023), 701–704
Pavel S. Gribanov, Daria V. Vorobyeva, Sergey D. Tokarev, Dmitry A. Loginov, Anastasya A. Danshina, Salekh M. Masoud, Sergey N. Osipov, “Rhodium(III)‐catalyzed Construction of D‐A Type Polyheteroaromatics with Fluorinated Benzothiadiazole as a Modifiable Acceptor Block”, Asian J Org Chem, 11:12 (2022)
Pavel S. Gribanov, Daria V. Vorobyeva, Sergey D. Tokarev, Dmitry A. Petropavlovskikh, Dmitry A. Loginov, Sergey E. Nefedov, Fedor M. Dolgushin, Sergey N. Osipov, “Rhodium‐Catalyzed C-H Activation/Annulation of Aryl Hydroxamates with Benzothiadiazol‐Containing Acetylenes: Access to Isoquinoline‐Bridged Donor‐Acceptor Luminophores”, Eur J Org Chem, 2022:13 (2022)
A. N. Chukhlantseva, M. V. Dmitriev, O. A. Maiorova, E. V. Shklyaeva, G. G. Abashev, “Synthesis and optical properties of new chalcones containing 4-[bis(2-hydroxyethyl)amino]phenyl fragment”, Mendeleev Commun., 32:2 (2022), 268–270
V. M. Korshunov, T. N. Chmovzh, G. R. Chkhetiani, I. V. Taidakov, O. A. Rakitin, “New D–A–D luminophores of the [1,2,5]thiadiazolo[3,4-d]pyridazine series”, Mendeleev Commun., 32:3 (2022), 371–373
O. V. Shurupova, G. K. Sterligov, M. A. Rasskazova, E. A. Drokin, A. N. Lysenko, S. A. Rzhevskiy, L. I. Minaeva, M. A. Topchiy, A. F. Asachenko, “One-pot two step synthesis of unsymmetrically substituted indenes from 3,4-diarylbutadiene sulfones”, Mendeleev Commun., 32:4 (2022), 446–448
Pavel S. Gribanov, Dmitry A. Loginov, Dmitry A. Lypenko, Artem V. Dmitriev, Sergey I. Pozin, Alexey E. Aleksandrov, Alexey R. Tameev, Igor L. Martynov, Andrey Yu. Chernyadyev, Sergey N. Osipov, “New Unsymmetrically Substituted Benzothiadiazole-Based Luminophores: Synthesis, Optical, Electrochemical Studies, Charge Transport, and Electroluminescent Characteristics”, Molecules, 26:24 (2021), 7596
S. A. Rzhevskiy, V. N. Bogachev, L. I. Minaeva, G. K. Sterligov, M. S. Nechaev, M. A. Topchiy, A. F. Asachenko, “Efficient synthesis of 3-arylbutadiene sulfones using the Heck–Matsuda reaction”, Mendeleev Commun., 31:4 (2021), 548–549