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Эта публикация цитируется в 5 научных статьях (всего в 5 статьях)
Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction
L. A. Bulyginaa, N. S. Khrushchevaa, K. A. Lyssenkobc, A. S. Peregudova a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
c G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
Аннотация:
New bicyclic unsymmetrical CNN palladium 5,6-membered pincer complex was synthesized from 3-ferrocenylmethyl-8-dimethylamino-3-azabicyclo[3.2.1]octane by its direct cyclopalladation with Li2PdCl or Na2PdCl4 and sodium acetate
in MeOH. The obtained complex exhibited high catalytic activity in the Suzuki cross-coupling between aryl bromides and phenylboronic acid.
Ключевые слова:
unsymmetrical pincer complexes, palladium complexes, ferrocene, bicyclic ligand precursor, Suzuki reaction.
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc653
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