Аннотация:
It has been shown that the C–F bond may be selectively hydrogenolysed under the action of HSiEt3 in the presence of AICI3, when the α-position of the C–F bond is occupied by a phenyl group or by a heteroatom with an unshared electron pair
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
M. E. Vol'pin, N. V. Shevchenko, G. I. Bolestova, I. G. Abramov, Yu. A. Fialkov, Z. N. Parnes, “Selective Hydrogenolysis of the C–F Bond”, Mendeleev Commun., 1:4 (1991), 118–119
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc5533
https://www.mathnet.ru/rus/mendc/v1/i4/p118
Эта публикация цитируется в следующих 11 статьяx:
Hendrik F. T. Klare, Lena Albers, Lars Süsse, Sebastian Keess, Thomas Müller, Martin Oestreich, “Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts”, Chem. Rev., 121:10 (2021), 5889
Hossein Robatjazi, Junwei Lucas Bao, Ming Zhang, Linan Zhou, Phillip Christopher, Emily A. Carter, Peter Nordlander, Naomi J. Halas, “Plasmon-driven carbon–fluorine (C(sp3)–F) bond activation with mechanistic insights into hot-carrier-mediated pathways”, Nat Catal, 3:7 (2020), 564
Kodai Saito, Taishi Umi, Takayuki Yamada, Takuya Suga, Takahiko Akiyama, “Niobium(v)-catalyzed defluorinative triallylation of α,α,α-trifluorotoluene derivatives by triple C–F bond activation”, Org. Biomol. Chem., 15:8 (2017), 1767
Nemanja Ðorđević, Madelyn Qin Yi Tay, Senthilkumar Muthaiah, Rakesh Ganguly, Dušan Dimić, Dragoslav Vidović, “C–F Bond Activation by Transient Phosphenium Dications”, Inorg. Chem., 54:9 (2015), 4180
Theresia Ahrens, Johannes Kohlmann, Mike Ahrens, Thomas Braun, “Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks”, Chem. Rev., 115:2 (2015), 931
Moritz F. Kuehnel, Dieter Lentz, Thomas Braun, “Synthese fluorierter Bausteine durch Übergangsmetall‐vermittelte Hydrodefluorierungsreaktionen”, Angewandte Chemie, 125:12 (2013), 3412
Moritz F. Kuehnel, Dieter Lentz, Thomas Braun, “Synthesis of Fluorinated Building Blocks by Transition‐Metal‐Mediated Hydrodefluorination Reactions”, Angew Chem Int Ed, 52:12 (2013), 3328
Timo Stahl, Hendrik F. T. Klare, Martin Oestreich, “Main-Group Lewis Acids for C–F Bond Activation”, ACS Catal., 3:7 (2013), 1578
Timo Stahl, Hendrik F. T. Klare, Martin Oestreich, “C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle”, J. Am. Chem. Soc., 135:4 (2013), 1248
Moritz F. Kuehnel, Philipp Holstein, Meike Kliche, Juliane Krüger, Stefan Matthies, Dominik Nitsch, Joseph Schutt, Michael Sparenberg, Dieter Lentz, “Titanium‐Catalyzed Vinylic and Allylic CF Bond Activation—Scope, Limitations and Mechanistic Insight”, Chemistry A European J, 18:34 (2012), 10701
M. E. VOL'PIN, N. V. SHEVCHENKO, G. I. BOLESTOVA, YU. V. ZEIFMAN, YU. A. FIALKOV, Z. N. PARNES, “ChemInform Abstract: Selective Hydrogenolysis of the C‐F Bond.”, ChemInform, 23:24 (1992)
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