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Эта публикация цитируется в 14 научных статьях (всего в 14 статьях)
Unexpected Oxidation of a Coordinated Phosphine Ligand. Synthesis and Molecular Structure of [Pd(μ-O2PPh2)(C6H5)(PPh3)]2
N. Yu. Kozitsynaa, A. M. Ellerna, M. Yu. Antipinb, Yu. T. Struchkovb, I. I. Moiseeva
a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
The reaction of [Pd(OAc)2(PPh3)]2 with HCO2H includes the transfer of an O atom from the carboxylic ligand to the P atom and cleavage of the P–Ph bond accompanied by transfer of the Ph group from PPh3 ligand to the palladium atom; the structure of the complex formed, [Pd(μ-O2PPh2)(C6H5)(PPh3)]2, has been resolved by X-ray analysis.
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https://www.mathnet.ru/rus/mendc5517
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