Эта публикация цитируется в 22 научных статьях (всего в 22 статьях)
Steric Effects in the Kinetics of Organometallic Reactions: A Time-Resolved Infrared Study of [(η5-C5R5)Mn(CO)2] (R = H, Me or Et) in n-heptane Solution
Аннотация:
Fast time-resolved IR spectroscopy (microsecond timescale) is used to record the spectra and kinetics of photochemical reactions of [(η5-C5R5)Mn(CO)3] (R = H, Me or Et) in n-heptane solution; second-order rate constants for reaction with H2, N2 and CO are ca. six times faster for [(C5Et5)Mn(CO)2(n-hept)] than for [(C5H5)Mn(CO)2(n-hept)] while the rate constants for the reaction of all three [(C5R5)Mn(CO)2(n-hept)] intermediates with PPh3 are almost identical.
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
F. P. Johnson, M. W. George, V. N. Bagratashvili, L. N. Vereshchagina, M. Poliakoff, “Steric Effects in the Kinetics of Organometallic Reactions: A Time-Resolved Infrared Study of [(η5-C5R5)Mn(CO)2] (R = H, Me or Et) in n-heptane Solution”, Mendeleev Commun., 1:1 (1991), 26–28
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc5477
https://www.mathnet.ru/rus/mendc/v1/i1/p26
Эта публикация цитируется в следующих 22 статьяx:
Rini Prakash, Alaka Nanda Pradhan, Madhuri Jash, Samia Kahlal, Marie Cordier, Thierry Roisnel, Jean-François Halet, Sundargopal Ghosh, “Diborane(6) and Its Analogues Stabilized by Mono-, Bi-, and Trinuclear Group 7 Templates: Combined Experimental and Theoretical Studies”, Inorg. Chem., 59:3 (2020), 1917
Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam, “Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(i) carbonyl complex”, Dalton Trans., 49:17 (2020), 5463
Qing Lu, Frank Neese, Giovanni Bistoni, “London dispersion effects in the coordination and activation of alkanes in σ-complexes: a local energy decomposition study”, Phys. Chem. Chem. Phys., 21:22 (2019), 11569
Mark D. Doherty, David C. Grills, Kuo-Wei Huang, James T. Muckerman, Dmitry E. Polyansky, Rudi van Eldik, Etsuko Fujita, “Kinetics and Thermodynamics of Small Molecule Binding to Pincer-PCP Rhodium(I) Complexes”, Inorg. Chem., 52:8 (2013), 4160
Carl R. Kemnitz, Eric S. Ball, Robert J. McMahon, “Photochemistry of CpMn(CO)3 and Related Derivatives: Spectroscopic Observation of Singlet and Triplet CpMn(CO)2”, Organometallics, 31:1 (2012), 70
James A. Calladine, Olga Torres, Mitch Anstey, Graham E. Ball, Robert G. Bergman, John Curley, Simon B. Duckett, Michael W. George, Amy I. Gilson, Douglas J. Lawes, Robin N. Perutz, Xue-Zhong Sun, K. Peter C. Vollhardt, “Photoinduced N2 loss as a route to long-lived organometallic alkane complexes: A time-resolved IR and NMR study”, Chem. Sci., 1:5 (2010), 622
Yasuro Kawano, Kazunori Yamaguchi, Shun‐ya Miyake, Taeko Kakizawa, Mamoru Shimoi, “Investigation of the Stability of the M‐H‐B Bond in Borane σ Complexes [M(CO)5(η1‐BH2R⋅L)] and [CpMn(CO)2(η1‐BH2R⋅L)] (M=Cr, W; L=Tertiary Amine or Phosphine): Substituent and Lewis Base Effects”, Chemistry A European J, 13:24 (2007), 6920
Alexander J. Cowan, Peter Portius, Hajime K. Kawanami, Omar S. Jina, David C. Grills, Xue-Zhong Sun, Jonathan McMaster, Michael W. George, “Time-resolved infrared (TRIR) study on the formation and reactivity of organometallic methane and ethane complexes in room temperature solution”, Proc. Natl. Acad. Sci. U.S.A., 104:17 (2007), 6933
Thomas E. Bitterwolf, “Annual review of organometallic and nitrosyl photochemistry: 2003”, Coordination Chemistry Reviews, 250:3-4 (2006), 388
Yasuro Kawano, Masahiro Hashiva, Mamoru Shimoi, “Syntheses and Reactivity of Cationic Borane-Ruthenium Complexes [(η5-C5R5)Ru(PMe3)2(η1-BH3·EMe3)][BArf4] (R = H, Me; E = N, P; BArf4 = [B{3,5-C6H3(CF3)2}4])”, Organometallics, 25:18 (2006), 4420
Leslie D. Field, Taian He, Paul Humphrey, Anthony F. Masters, Peter Turner, “Manganese complexes of the pentaphenylcyclopentadienyl ligand”, Polyhedron, 25:7 (2006), 1498
David C. Grills, Kuo-Wei Huang, James T. Muckerman, Etsuko Fujita, “Kinetic studies of the photoinduced formation of transition metal–dinitrogen complexes using time-resolved infrared and UV–vis spectroscopy”, Coordination Chemistry Reviews, 250:13-14 (2006), 1681
Metal Dihydrogen and σ-Bond Complexes, 2002, 207
Taeko Kakizawa, Yasuro Kawano, Mamoru Shimoi, “Syntheses and Structures of Manganese Complexes of Borane-Lewis Base Adducts, [CpMn(CO)2(η1-BH3·L)] (L = NMe3, PMe3)”, Organometallics, 20:15 (2001), 3211
David C. Grills, Xue Z. Sun, Gavin I. Childs, Michael W. George, “An Investigation into the Reactivity of Organometallic Noble Gas Complexes: A Time-Resolved Infrared Study in Supercritical Noble Gas and Alkane Solution at Room Temperature”, J. Phys. Chem. A, 104:18 (2000), 4300
Xue-Zhong Sun, David C. Grills, Sergei M. Nikiforov, Martyn Poliakoff, Michael W. George, “Remarkable Stability of (η5-C5H5)Re(CO)2L (L = n-Heptane, Xe, and Kr): A Time-Resolved Infrared Spectroscopic Study of (η5-C5H5)Re(CO)3 in Conventional and Supercritical Fluid Solution”, J. Am. Chem. Soc., 119:32 (1997), 7521
Chris Hall, Robin N. Perutz, “Transition Metal Alkane Complexes†”, Chem. Rev., 96:8 (1996), 3125
James A. Banister, Michael W. George, Stefanie Grubert, Steven M. Howdle, Margaret Jobling, Frank P.A. Johnson, Sara L. Morrison, Martyn Poliakoff, Ulrich Schubert, Jeremy R. Westwell, “Organometallic photochemistry in supercritical fluids: Reactions of cyclopentadienyl carbonyl and phosphine carbonyl complexes of manganese with dinitrogen”, Journal of Organometallic Chemistry, 484:1-2 (1994), 129
David White, Neil J. Coville, Advances in Organometallic Chemistry, 36, 1994, 95
Обратная связь: