Аннотация:
Addition of alkali strongly accelerates the oxidation of cyciohexane by an iron tetramesitylporphyrin−NaOCl system, the selectivity of the reaction and the H−D kinetic isotope effect also being affected; possible mechanisms of OH− action are discussed
Тип публикации:
Статья
Язык публикации: английский
Образец цитирования:
A. B. Sorokin, A. M. Khenkin, A. E. Shilov, “Base Acceleration of Alkane Oxidation by an Iron-porphyrin−Hypochlorite System. Activity, Selectivity and Kinetic Isotope Effect”, Mendeleev Commun., 2:4 (1992), 137–139
Образцы ссылок на эту страницу:
https://www.mathnet.ru/rus/mendc5443
https://www.mathnet.ru/rus/mendc/v2/i4/p137
Эта публикация цитируется в следующих 6 статьяx:
Cancheng Guo, Qingjing Peng, Qiang Liu, Guofang Jiang, “Selective oxidation of ethylbenzene with air catalyzed by simple μ-oxo dimeric metalloporphyrins under mild conditions in the absence of additives”, Journal of Molecular Catalysis A: Chemical, 192:1-2 (2003), 295
Can-Cheng Guo, Jian-Xin Song, Xin-Bin Chen, Guo-Fang Jiang, “A new evidence of the high-valent oxo–metal radical cation intermediate and hydrogen radical abstract mechanism in hydrocarbon hydroxylation catalyzed by metalloporphyrins”, Journal of Molecular Catalysis A: Chemical, 157:1-2 (2000), 31
Can-Cheng Guo, He-Ping Li, Jian-Bing Xu, “Study of Synthesis of μ-Oxo-bismanganese(III)Porphyrin Compounds and Their Catalysis of Cyclohexane Oxidation by PhIO”, Journal of Catalysis, 185:2 (1999), 345
Ferenc Ungváry, “Transition metals in organic synthesis: hydroformylation, reduction, and oxidation. Annual survey covering the year 1993”, Coordination Chemistry Reviews, 141 (1995), 371
A. A. Shteinman, “Oxygen transfer catalysis by chemical analogs of monooxygenases”, Russ Chem Bull, 42:2 (1993), 227
A. B. SOROKIN, A. M. KHENKIN, A. E. SHILOV, “ChemInform Abstract: Base Acceleration of Alkane Oxidation by an Iron‐Porphyrin ‐ Hypochlorite System. Activity, Selectivity, and Kinetic Isotope Effect.”, ChemInform, 24:15 (1993)
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