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Эта публикация цитируется в 9 научных статьях (всего в 9 статьях)
The Selective Thermal Fragmentation of 2,2'-Dipropynyl Sulfide to Propynethial and Allene
O. M. Nefedova, M. A. Koroleva, L. Zanathyb, B. Soloukic, H. Bockc
a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Institute of General and Inorganic Chemistry, Eotvos University, Budapest, Hungary
c Institute of Inorganic Chemistry, Johann Wolfgang Goethe-University, Frankfurt, Germany
Аннотация:
The thermolysis of 2,2'-dipropynyl sulfide in a flow system under almost unimolecular conditions, which above 830 K selectively yields propynethial and allene, is optimized by photoelectron spectroscopic real-time gas analysis and, according to semiempirical energy hypersurface calculations, possibly proceeds via an intramolecular hydrogen transfer.
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https://www.mathnet.ru/rus/mendc5409
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