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Эта публикация цитируется в 14 научных статьях (всего в 14 статьях)
Matrix Isolation and Photochemical Interconversion of Silacyclopentadienes
V. N. Khabasheskua, V. Balajia, S. E. Boganovb, S. A. Bashkirovac, P. M. Matveichevc, E. A. Chernyshevc, O. M. Nefedovb, J. Michla
a Department of Chemistry and Biochemistry, University of Colorado at Boulder, Boulder, USA
b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
c State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russian Federation
Аннотация:
1-Silacyclopenta-2,4-diene 1 has been generated by vacuum pyrolysis of 5-silaspiro[4.4]nona-2,7-diene 5 and by photolysis of matrix-isolated 1,1-diazido-1-silacyclopent-3-ene 6, and characterized by matrix-isolated IR and UV spectroscopy; reversible interconversion of 1 with 1-silacyclopenta-1,3-diene 2, 1-silacyclopenta-1,4-diene 3 and 1-silacyclopent-3-ene-1,1-diyl 4 has been observed upon irradiation at various wavelengths; the red-shifted UV absorption of 2 and 3, together with their low Si-C-C-C π conjugation.
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https://www.mathnet.ru/rus/mendc5389
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