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Эта публикация цитируется в 6 научных статьях (всего в 6 статьях)
The First Example of Electrophilic Mercuration of Icosahedral Dicobaltacarborane 3,6-Cp2-3,6,1,2-Co2C2B8H10
A. Ya. Usiatinsky, O. M. Khitrova, P. V. Petrovskii, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov, V. I. Bregadze
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Аннотация:
The interaction of equivalent amounts of 3,6-Cp2-3,6,1,2-Co2C2B8H10 1 and mercury(II) acetate in boiling CH2Cl2 followed by treatment with NaCl results in a mixture (1:1.2) of 8- and 9-chloromercury derivatives of dicobaltacarboranes (compounds 2 and 3). The action of excess Hg(OAc)2 on 1 leads to the tetramercurated compound with substitution in positions 8, 9, 10 and 12 of the carborH10 1 and mercury(II) acetate in boiling CH2Cl2 followed by treatment with NaCl results in a mixture (1:1.2) of 8- and 9-chlo
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